Hydrometallurgical Processes for the Recovery of Rare Earths, Nickel and Cobalt in Chloride Medium

被引:1
作者
Lakshmanan, V. I. [1 ]
Sridhar, R. [1 ]
Tait, D. [1 ]
Halim, M. A. [1 ]
机构
[1] Proc Res ORTECH Inc, 2350 Sheridan Pk Dr, Mississauga, ON L5K 2T4, Canada
来源
APPLICATIONS OF PROCESS ENGINEERING PRINCIPLES IN MATERIALS PROCESSING, ENERGY AND ENVIRONMENTAL TECHNOLOGIES | 2017年
关键词
Rare earths; Nickel; Cobalt; Laterite; Mixed chloride; Atmospheric leaching; Solvent extraction; EXTRACTION;
D O I
10.1007/978-3-319-51091-0_15
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Rare earth elements (REEs), nickel and cobalt find their use in developing strategic materials and their demand is consistently increasing in the world while the extractable ores of these metals are gradually depleting. Process Research ORTECH Inc. (PRO) has developed innovative mixed chloride leaching processes for the recovery of REEs from alumino-silicate ores, and nickel and cobalt from laterite ores. The addition of magnesium chloride in hydrochloric acid enhances the activity of the hydrogen ion by orders of magnitude, which permit rapid leaching rates at moderate temperature and atmospheric pressure, along with high metal recovery. Innovative solvent extraction process steps are used for the separation of these metals from pregnant leach solutions. PRO's processes also produce value added by-product of high purity iron oxide and recycle chloride lixiviant to the leaching stage. This paper describes the leaching and separation reaction mechanisms and potential process flowsheets.
引用
收藏
页码:169 / 177
页数:9
相关论文
共 24 条
[1]  
Adham K., 2006, Iron Control Technologies, Proceedings of the Third International Symposium on Iron Control in Hydrometallurgy, 36th Annual CIM Hydrometallurgical Meeting, P815
[2]  
Baerhold F., 2006, Iron Control Technologies, Proceedings of the Third International Symposium on Iron Control in Hydrometallurgy, 36th Annual CIM Hydrometallurgical Meeting, P789
[3]  
Christie PG., 1976, Hydrometallurgy, V2, P105
[4]  
Cox M., 2004, Solvent Extraction Principles and Practice, V2, P1, DOI DOI 10.1201/9780203021460
[5]  
Harris G.B., 2004, HYDR 2004 INT C HYDR, P384
[6]  
Harris G.B., 2010, US Patent, No, Patent No. [7736606 B2, 7736606]
[7]  
Harris G.B., 2011, Canadian Patent, No, Patent No. 2478516
[9]   Properties of electrolyte solutions relevant to high concentration chloride leaching.: II.: Density, viscosity and heat capacity of mixed aqueous solutions of magnesium chloride and nickel chloride measured to 90 °C [J].
Koenigsberger, E. ;
Koenigsberger, L. -C. ;
May, P. ;
Harris, B. .
HYDROMETALLURGY, 2008, 90 (2-4) :168-176
[10]  
Lakshmanan V. I., 2015, [No title captured], Patent No. [US 9,115,419 B2, 9115419]