Reactions of Distibanes with [Fe2(CO)9]: Synthesis, Structure and DFT Calculations of [(Et2Sb)4Fe4(CO)14], [(nPr2Sb)4Fe3(CO)10], [{(Me3SiCH2)2Sb}4Fe2(CO)6], and [2-(Me2NCH2)C6H4SbFe2(CO)8]

被引：3

作者：

Breunig, Hans J. ^{[1
]}

Lork, Enno ^{[1
]}

Moldovan, Ovidiu ^{[1
]}

Rat, Ciprian I. ^{[2
]}

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany

[2] Univ Babes Bolyai, Fac Chim Ingn Chim, Cluj Napoca 400028, Romania

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 06期

关键词：

Antimony; Iron; Heterometallic complexes; X-ray diffraction; Density functional calculations; METAL CARBONYLS; MOLECULAR-STRUCTURES; IRON COMPLEXES; PHOSPHORUS; CHEMISTRY; LIGANDS; MO;

D O I：

10.1002/zaac.200900547

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iron complexes [(Et2Sb)(4)Fe-4(CO)(14)] (1), [(nPr(2)Sb)(4)Fe-3-(CO)(10)] (2), [{(Me3SiCH2)(2)Sb}(4)Fe-2(CO)(6)] (3), and [2-(Me2NCH2)-C6H4SbFe2(CO)(8)] (4) were prepared by reactions of distibanes with Fe-2(CO)(9). Compounds 1-4 were characterized by X-ray diffraction, H-1-NMR and IR spectroscopy as well as mass spectrometry; complex 1 was additionally characterized by density functional calculations.

引用

页码：1090 / 1094

页数：5

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