Simple model for the calculation of total cross sections for electron scattering from polyatomic molecules

被引:39
作者
Jiang, YH [1 ]
Sun, JF [1 ]
Wan, LD [1 ]
机构
[1] HENAN NORMAL UNIV,DEPT PHYS,XINXIANG 453002,PEOPLES R CHINA
关键词
D O I
10.1088/0953-4075/30/21/033
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The previously used additivity rule has been modified by considering the geometric shielding effect of molecules. Total cross sections (TCSs) for electron scattering from hydrocarbon molecules (C2H2,C2H4,C2H6,C3H6,C3H8 and C4H10) are calculated in 10-1000 eV employing this semiempirical approach. The atoms are presented by spherical complex optical potential which is composed of static, exchange, polarization, and absorption terms. Compared with our earlier results, the modified additivity rule for the TCS on complex polyatomic molecules is simple but more effective and it yields better accord with experiments in the intermediate and high energy region.
引用
收藏
页码:5025 / 5032
页数:8
相关论文
共 21 条
[1]   SIMPLE-MODELS FOR THE CALCULATION OF PHOTOIONIZATION AND ELECTRON-IMPACT IONIZATION CROSS-SECTIONS OF POLYATOMIC-MOLECULES [J].
BOBELDIJK, M ;
VANDERZANDE, WJ ;
KISTEMAKER, PG .
CHEMICAL PHYSICS, 1994, 179 (02) :125-130
[2]  
CHRISTOPHOROU LG, 1984, ELECTRON MOL INTERAC, V2
[3]   TOTAL CROSS-SECTION MEASUREMENTS FOR POSITRON AND ELECTRON-SCATTERING ON HYDROCARBONS BETWEEN 5-EV AND 400-EV [J].
FLOEDER, K ;
FROMME, D ;
RAITH, W ;
SCHWAB, A ;
SINAPIUS, G .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1985, 18 (16) :3347-3359
[4]   Total cross sections for electron scattering by CO2 molecules in the energy range 400-5000 eV [J].
Garcia, G ;
Manero, E .
PHYSICAL REVIEW A, 1996, 53 (01) :250-254
[5]   TOTAL (ELASTIC PLUS INELASTIC) CROSS-SECTIONS FOR ELECTRON-SCATTERING FROM DIATOMIC AND POLYATOMIC-MOLECULES AT 10-EV-5000-EV - H2, LI2, HF, CH4, N2, CO, C2H2, HCN, O2, HCL, H2S, PH3, SIH4, AND CO2 [J].
JAIN, A ;
BALUJA, KL .
PHYSICAL REVIEW A, 1992, 45 (01) :202-218
[6]   TOTAL CROSS-SECTIONS FOR ELECTRON-SCATTERING BY POLYATOMIC-MOLECULES AT 10-1000 EV - C2H2, C2H4, C2H6, C3H6, C3H8 AND C4H8 [J].
JIANG, YH ;
SUN, JF ;
WAN, L .
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1995, 34 (01) :29-33
[7]   Total electron scattering cross sections for NO, CO, NO2, N2O, CO2 and NH3 (E(i)>=50 eV) [J].
Joshipura, KN ;
Patel, PM .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1996, 29 (17) :3925-3932
[8]  
Mark TD., 1985, Electron Impact Ionization
[9]   ADDITIVITY METHODS IN MOLECULAR POLARIZABILITY [J].
MILLER, KJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (23) :8533-8542
[10]   SOME ASPECTS OF TOTAL SCATTERING CROSS-SECTIONS OF ELECTRONS FOR SIMPLE HYDROCARBON MOLECULES [J].
NISHIMURA, H ;
TAWARA, H .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1991, 24 (15) :L363-L366