1,2-Dihydroxy-2-(3-methylbut-2-enyl)-3-oxo-2,3-dihydro-1H-indene-1-carboxylic acid monohydrate

被引：8

作者：

Franscisco, Acacio Ivo ^{[2
]}

Silveira, Gleiciani de Q. ^{[2
]}

Resende, Jackson A. L. C. ^{[2
]}

Balliano, Tatiane L. ^{[1
]}

Malta, Valeria R. S. ^{[1
]}

Pinto, Antonio Ventura ^{[3
]}

机构：

[1] Univ Fed Alagoas, Inst Quim & Biotecnol, BR-57072970 Maceio, Al, Brazil

[2] Univ Fed Fluminense, Inst Quim, BR-24020150 Niteroi, RJ, Brazil

[3] Univ Fed Rio de Janeiro, Nucleo Pesquisas Prod Nat, BR-21944971 Rio De Janeiro, Brazil

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

POTASSIUM-PERMANGANATE; HOOKER OXIDATION; DERIVATIVES; MECHANISM;

D O I：

10.1107/S1600536810000516

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C(15)H(16)O(5)center dot H(2)O, is an intermediate of the Hooker oxidation reaction, used for the synthesis of 2-hydroxy-3-(2-methylprop-1-enyl)naphthalene-1,4-dione (norlapachol). The packing in the crystal structure is arranged by an O-H center dot center dot center dot O hydrogen-bonded network along the [100] and [010] directions. Each organic molecule is linked to four other molecules via the hydroxy groups. The water solvent molecule is connected to carboxylic acid groups by three hydrogen bonds.

引用

页码：O341 / U2279

页数：10

共 14 条

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