Pd-Catalyzed Selective B(6)-H Phosphorization of nido-Carboranes via Cascade Deboronation/B-H Activation from closo-Carboranes

被引：11

作者：

Sun, Chaofan ^{[1
]}

Lu, Ju-You ^{[1
]}

Lu, Jian ^{[2
]}

机构：

[1] Hainan Univ, Sch Sci, Minist Educ Adv Mat Trop Isl Resources, Key Lab, Haikou 570228, Hainan, Peoples R China

[2] Xian Modern Chem Res Inst, State Key Lab Fluorine & Nitrogen Chem, Xian 710065, Peoples R China

来源：

INORGANIC CHEMISTRY | 2022年 / 61卷 / 25期

基金：

海南省自然科学基金;

关键词：

ICOSAHEDRAL CARBORANES; MOLECULAR-STRUCTURE; O-CARBORANES; COMPLEXES; ARYLATION; LIGANDS; BORON; MONOPHOSPHINOCARBORANES; REARRANGEMENT; DERIVATIVES;

D O I：

10.1021/acs.inorgchem.2c00993

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Efficient Pd-catalyzed regioselective B(6)-H phosphorization of nido-carboranes via cascade deboronation/B-H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in combination with pyridine ligands has been developed, affording unprecedented B(6)-phosphinated nido-carborane derivatives with high selectivity in a simple one-pot process.

引用

页码：9623 / 9630

页数：8

共 50 条

[41] Acid-Induced Opening of [closo-B10H10]2- as a New Route to 6-Substituted nido-B10H13 Decaboranes and Related Carboranes [J].

Bondarev, Oleg ;

Sevryugina, Yulia V. ;

Jalisatgi, Satish S. ;

Hawthorne, M. Frederick .

INORGANIC CHEMISTRY, 2012, 51 (18) :9935-9942

[42] A variable bidentate traceless directing group for nickel-catalyzed regioselective B-H poly-chalcogenation of o-carboranes [J].

Li, Ping ;

Qiu, Zihuan ;

Lu, Jian ;

Lu, Ju-You .

INORGANIC CHEMISTRY FRONTIERS, 2025, 12 (05) :1994-2002

[43] Rh-Catalyzed Regioselective Dialkylation of Cage B-H bonds in o-Carboranes: Oxidative Heck Reactions via an Enol Isomerization [J].

Wang, Qian ;

Tian, Song ;

Zhang, Chuyi ;

Li, Jiangwei ;

Wang, Zhixuan ;

Du, Yongmei ;

Zhou, Ling ;

Lu, Jian .

ORGANIC LETTERS, 2019, 21 (19) :8018-8021

[44] Palladium catalyzed regioselective mono-alkenylation of o-carboranes via Heck type coupling reaction of a cage B-H bond [J].

Wu, Ji ;

Cao, Ke ;

Xu, Tao-Tao ;

Zhang, Xiao-Juan ;

Jiang, Linhai ;

Yang, Junxiao ;

Huang, Yawen .

RSC ADVANCES, 2015, 5 (111) :91683-91685

[45] Coordination chemistry of thioether-carboranes in polynuclear metal carbonyl cluster complexes. B-H activation of thioether-carboranes by dirhenium carbonyl complexes [J].

Adams, Richard D. ;

Kiprotich, Joseph .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 865 :23-28

[46] Regioselective Nucleophilic Alkylation/Arylation of B-H Bonds in o-Carboranes: An Alternative Method for Selective Cage Boron Functionalization [J].

Tang, Cen ;

Zhang, Jiji ;

Zhang, Jie ;

Xie, Zuowei .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (48) :16423-16427

[47] Pd-Catalyzed One-Pot Synthesis of Difunctionalized σ-Carboranes via Construction of B-C and B-Heteroatom Bonds [J].

Ge Yixiu ;

Qiu Zaozao ;

Xie Zuowei .

ACTA CHIMICA SINICA, 2022, 80 (04) :432-437

[48] Electronic Effect-Guided, Palladium-Catalyzed Regioselective B-H Activation and Multistep Diarylation of o-Carboranes with Aryl Iodides [J].

Mu, Wei-Hua ;

Liu, Wen-Zhu ;

Cheng, Rui-Jiao ;

Fang, De-Cai .

ACS OMEGA, 2019, 4 (01) :465-474

[49] Transition Metal Catalyzed, Regioselective B(4)-Halogenation and B(4,5)-Diiodination of Cage B-H Bonds in o-Carboranes [J].

Lyu, Hairong ;

Quan, Yangjian ;

Xie, Zuowei .

CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (59) :14866-14871

[50] Transition metal catalyzed selective B(3)-H or B(4)-H amination of o-carboranes via dehydrogenative BH/NH cross-coupling [J].

Lyu, Hairong ;

Xie, Zuowei .

CHEMICAL COMMUNICATIONS, 2022, 58 (60) :8392-8395

← 1 2 3 4 5 →