Pd-Catalyzed Selective B(6)-H Phosphorization of nido-Carboranes via Cascade Deboronation/B-H Activation from closo-Carboranes

被引：11

作者：

Sun, Chaofan ^{[1
]}

Lu, Ju-You ^{[1
]}

Lu, Jian ^{[2
]}

机构：

[1] Hainan Univ, Sch Sci, Minist Educ Adv Mat Trop Isl Resources, Key Lab, Haikou 570228, Hainan, Peoples R China

[2] Xian Modern Chem Res Inst, State Key Lab Fluorine & Nitrogen Chem, Xian 710065, Peoples R China

来源：

INORGANIC CHEMISTRY | 2022年 / 61卷 / 25期

基金：

海南省自然科学基金;

关键词：

ICOSAHEDRAL CARBORANES; MOLECULAR-STRUCTURE; O-CARBORANES; COMPLEXES; ARYLATION; LIGANDS; BORON; MONOPHOSPHINOCARBORANES; REARRANGEMENT; DERIVATIVES;

D O I：

10.1021/acs.inorgchem.2c00993

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Efficient Pd-catalyzed regioselective B(6)-H phosphorization of nido-carboranes via cascade deboronation/B-H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in combination with pyridine ligands has been developed, affording unprecedented B(6)-phosphinated nido-carborane derivatives with high selectivity in a simple one-pot process.

引用

收藏

页码：9623 / 9630

页数：8

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