High pressure mediated asymmetric Diels-Alder reaction of chiral sulfinylacrylate derivatives with furan and 2-methoxyfuran

被引：0

作者：

Yamakoshi, YN

Ge, WY

Sugita, J

Okayama, K

Takahashi, T

Koizumi, T

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来源：

HETEROCYCLES | 1996年 / 42卷 / 01期

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中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric Diels-Alder reaction of chiral sulfinylacrylate derivatives (1 and 2) with furan (3) and 2-methoxyfuran (4) proceeded under high pressure (1.2 GPa) conditions to give endo cycloadducts(6c-f). The absolute configuration of adduct (6) was confirmed by conversion of 6e to (-)-COTC (9).

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页码：129 / 133

页数：5

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