Ag-Based Catalysts in Heterogeneous Selective Oxidation of Alcohols: A Review

被引：72

作者：

Torbina, Viktoriia V. ^{[1
]}

Vodyankin, Andrei A. ^{[1
]}

Ten, Sergey ^{[1
]}

Mamontov, Grigory V. ^{[1
]}

Salaev, Mikhail A. ^{[1
]}

Sobolev, Vladimir I. ^{[2
]}

Vodyankina, Olga V. ^{[1
]}

机构：

[1] Tomsk State Univ, Lab Catalyt Res, 36 Lenin Ave, Tomsk 634050, Russia

[2] Russian Acad Sci, Boreskov Inst Catalysis, Pr Akademika Lavrentieva 5, Novosibirsk 630090, Russia

来源：

CATALYSTS | 2018年 / 8卷 / 10期

关键词：

heterogeneous catalysis; selective oxidation of alcohols; mono- and polyalcohols; silver catalyst; Ag nanoparticles; gas-phase and liquid-phase oxidation of alcohols; photooxidation; GAS-PHASE OXIDATION; ETHYLENE-GLYCOL OXIDATION; STRUCTURED SILVER CATALYST; TERT-BUTYL HYDROPEROXIDE; BENZYL ALCOHOL; LIQUID-PHASE; AEROBIC OXIDATION; ELECTROLYTIC SILVER; ALLOY NANOPARTICLES; METHANOL OXIDATION;

D O I：

10.3390/catal8100447

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alcohols (bioalcohols) is a class of chemicals that are used as a feedstock for the manufacturing of a large number of valuable intermediates in industrially important processes. Currently, sustainable technologies for selective conversion of alcohols utilize green oxidants, mainly, ambient air or oxygen. Due to the high affinity of oxygen towards silver, the latter serves as an active component of supported heterogeneous catalysts. In this review, we consider Ag-based catalysts that participate in gas- or liquid-phase oxidation of alcohols. Oxidation of methanol, ethanol, ethylene glycol, propylene glycol, glycerol, benzyl and allyl alcohols is mostly considered. A particular attention is paid to selective photooxidation of alcohols over Ag-based catalysts. We discuss the catalyst composition in terms of (1) the state of the active component, (2) the nature of the substrate, (3) support nature, and (4) the strength of the metal-support interactions.

引用

页数：54

共 50 条

[41] Selective liquid-phase oxidation of alcohols catalyzed by a silver-based catalyst promoted by the presence of ceria [J].

Beier, Matthias J. ;

Hansen, Thomas W. ;

Grunwaldt, Jan-Dierk .

JOURNAL OF CATALYSIS, 2009, 266 (02) :320-330

[42] Liquid Phase Selective Oxidation of Alcohols over VPO Catalysts Supported on Mesoporous Hexagonal Molecular Sieves (HMS) [J].

Mahdavi, Vahid ;

Hasheminasab, Hamid Reza ;

Abdollahi, Sohrab .

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2010, 57 (02) :189-198

[43] Selective benzylic oxidation of alkyl substituted aromatics to ketones over Ag/SBA-15 catalysts [J].

Anand, Narani ;

Reddy, Kannapu Hari Prasad ;

Prasad, Ganjala Venkata Siva ;

Rao, Kamaraju Seetha Rama ;

Burri, David Raju .

CATALYSIS COMMUNICATIONS, 2012, 23 :5-9

[44] Efficient and selective aerobic oxidation of alcohols catalysed by MOF-derived Co catalysts [J].

Bai, Cuihua ;

Li, Aiqin ;

Yao, Xianfang ;

Liu, Hongli ;

Li, Yingwei .

GREEN CHEMISTRY, 2016, 18 (04) :1061-1069

[45] Oxygen-Rich Carbon Quantum Dots as Catalysts for Selective Oxidation of Amines and Alcohols [J].

Ye, Jianglin ;

Ni, Kun ;

Liu, Jie ;

Chen, Guanxiong ;

Ikram, Mujtaba ;

Zhu, Yanwu .

CHEMCATCHEM, 2018, 10 (01) :259-265

[46] Sol-gel ormosils doped with TEMPO as recyclable catalysts for the selective oxidation of alcohols [J].

Ciriminna, R ;

Bolm, C ;

Fey, T ;

Pagliaro, M .

ADVANCED SYNTHESIS & CATALYSIS, 2002, 344 (02) :159-163

[47] Silver Catalysts for the Partial Oxidation of Alcohols [J].

Vodyankina, O. V. .

CATALYSIS IN INDUSTRY, 2022, 14 (03) :314-326

[48] Oxidation of alcohols over vanadium catalysts [J].

Trakarnpruk, Wimonrat ;

Hoonsart, Piyanoot .

CHINESE JOURNAL OF CATALYSIS, 2007, 28 (04) :290-292

[49] Oxidation of alcohols using RuMnCe catalysts [J].

Checinski, Marek Pawel ;

Brueckner, Angelika ;

Radnik, Joerg ;

Koeckritz, Angela .

APPLIED CATALYSIS A-GENERAL, 2009, 366 (01) :212-219

[50] Preparation of Ruthenium Incorporated Heterogeneous Catalysts Using Hydroxyapatite as Catalytic Supports for Aerobic Oxidation of Alcohols [J].

Kim, Sohee ;

Jung, Jong-Hwa ;

Kim, Dong-Hee ;

Woo, Dong Kyun ;

Park, Joon B. ;

Choi, Myong Yong ;

Kwon, Ki-Young .

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2013, 34 (01) :221-224

← 1 2 3 4 5 →