Unstrained Carbon-Carbon Bond Cleavage

被引：120

作者：

Liu, Hui ^{[1
,2
]}

Feng, Minghao ^{[1
]}

Jiang, Xuefeng ^{[1
,3
,4
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[2] Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China

[3] Peking Univ, BNLMS, Beijing 100871, Peoples R China

[4] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2014年 / 9卷 / 12期

关键词：

CC activation; metal-free synthesis; synthesis design; transition metals; unstrained CC bonds; C-C-BOND; AEROBIC OXIDATIVE CLEAVAGE; TRIPLE BOND; CATALYZED CLEAVAGE; METAL-FREE; MOLECULAR-OXYGEN; H ACTIVATION; INTRAMOLECULAR ARYLCYANATION; MECHANISTIC INSIGHT; ALLYLIC ALCOHOLS;

D O I：

10.1002/asia.201402591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Focus Review presents recent developments in the cleavage of CC bonds in organic molecules. Significant progress in CC activation, including the development of a variety of new synthetic strategies, has contributed to the development of this field over the past few decades. Transition-metal-mediated CC bond cleavage has been shown to be a quite efficient process and several elegant metal-free methods have also recently been developed. Strained rings have been widely used in CC cleavage transformations; however, unstrained CC activation has increasingly caught the attention of organic researchers, which inspired us to clarify the developments in this field.

引用

页码：3360 / 3389

页数：30

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