Influence of Synthesis Conditions on the Physicochemical Properties of Poly-2-[(2E)-1-methyl-2-buten-1-yl]aniline

被引：7

作者：

Andriianova, A. N. ^{[1
,2
]}

Gribko, D. E. ^{[1
]}

Mullagaliev, I. N. ^{[1
]}

Salikhov, R. B. ^{[1
]}

Mustafin, A. G. ^{[1
,2
]}

机构：

[1] Bashkir State Univ, Ufa 450076, Russia

[2] Russian Acad Sci, Ufa Fed Res Ctr, Ufa Inst Chem, Ufa 450054, Russia

来源：

POLYMER SCIENCE SERIES B | 2021年 / 63卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

POLYANILINE;

D O I：

10.1134/S1560090421020032

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new polymer, poly-2-(1-methylbut-2-en-1-yl)aniline, is synthesized using doping and oxidizing agents. The influence of its preparation conditions on the physicochemical properties of materials is considered. The morphology of polymers is investigated by scanning electron microscopy, their solubility and IR and UV spectral characteristics are studied, and the photoluminescent properties are revealed. It is shown that the properties of the polymer depend on the nature of the doping agent. It is found that the use of FeCl3 as an oxidizing agent makes it possible to obtain the material in the doped form and with the highest luminescence intensity. The synthesized polymers are tested as an active material in moisture sensors.

引用

页码：135 / 141

页数：7

共 22 条

[1] Synthesis and Physico-chemical Properties of (Co)polymers of 2-[(2E)-1-methyl-2-buten-1-yl]aniline and Aniline [J].

Andriianova, A. ;

Shigapova, A. ;

Biglova, Y. ;

Salikhov, R. ;

Abdrakhmanov, I ;

Mustafin, A. .

CHINESE JOURNAL OF POLYMER SCIENCE, 2019, 37 (08) :774-782

[2] Effect of structural factors on the physicochemical properties of functionalized polyanilines [J].

Andriianova, Anastasiia N. ;

Biglova, Yuliya N. ;

Mustafin, Akhat G. .

RSC ADVANCES, 2020, 10 (13) :7468-7491

[3] Effect of Cobalt Phthalocyanine on Synthesis and Physicochemical Properties of Polyaniline [J].

Andriianova, Anastasiia N. ;

Mustafin, Akhat G. ;

Abdrakhmanov, Ildus B. .

CHEMISTRYSELECT, 2019, 4 (38) :11307-11314

[4] Novel synthetic methods to produce functionalized conducting polymers I. Polyanilines [J].

Barbero, C ;

Salavagione, HJ ;

Acevedo, DF ;

Grumelli, DE ;

Garay, F ;

Planes, GA ;

Morales, GM ;

Miras, MC .

ELECTROCHIMICA ACTA, 2004, 49 (22-23) :3671-3686

[5] Progress in preparation, processing and applications of polyaniline [J].

Bhadra, Sambhu ;

Khastgir, Dipak ;

Singha, Nikhil K. ;

Lee, Joong Hee .

PROGRESS IN POLYMER SCIENCE, 2009, 34 (08) :783-810

[6] Preparation and investigation of soluble functionalized polyanilines [J].

Biglova, Yu. N. ;

Salikhov, R. B. ;

Abdrakhmanov, I. B. ;

Salikhov, T. R. ;

Safargalin, I. N. ;

Mustafin, A. G. .

PHYSICS OF THE SOLID STATE, 2017, 59 (06) :1253-1259

[7] Recent advances in polyaniline research: Polymerization mechanisms, structural aspects, properties and applications [J].

Ciric-Marjanovic, Gordana .

SYNTHETIC METALS, 2013, 177 :1-47

[8] POLYANILINE - A HISTORICAL SURVEY [J].

GENIES, EM ;

BOYLE, A ;

LAPKOWSKI, M ;

TSINTAVIS, C .

SYNTHETIC METALS, 1990, 36 (02) :139-182

[9]

Inzelt G., 2008, Conducting Polymers: A New Era in Electrochemistry

[10] Synthesis and physicochemical properties of poly[2-(2-chloro-1-methylbut-2-en-1-yl)aniline] obtained with various dopants [J].

Latypova, Lyaysan R. ;

Andriianova, Anastasiia N. ;

Salikhov, Shamil M. ;

Mullagaliev, Ilnur N. ;

Salikhov, Renat B. ;

Abdrakhmanov, Ildus B. ;

Mustafin, Akhat G. .

POLYMER INTERNATIONAL, 2020, 69 (09) :804-812

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