Liquid clathrate formation in ionic liquid-aromatic mixtures

被引：381

作者：

Holbrey, JD

Reichert, WM

Nieuwenhuyzen, M

Sheppard, O

Hardacre, C

Rogers, RD ^{[1
]}

机构：

[1] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA

[2] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

[3] Queens Univ Belfast, Dept Chem, Belfast BT9 5AG, Antrim, North Ireland

[4] Queens Univ Belfast, QUILL, Belfast BT9 5AG, Antrim, North Ireland

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 04期

关键词：

D O I：

10.1039/b212726a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate-benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2: 1 inclusion compound.

引用

收藏

页码：476 / 477

页数：2

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