Dipole moment and self-association of cyclohexylsulfamic acid in 1,4-dioxane solution at 298.15 K

被引:1
作者
Klofutar, Cveto [1 ]
Ajnihar, Mateja [1 ]
Ulrih, Natasa Poklar [1 ]
Rudan-Tasic, Darja [1 ,2 ]
机构
[1] Univ Ljubljana, Biotech Fac, Ljubljana 1000, Slovenia
[2] Krog MIT, Ljubljana 1000, Slovenia
来源
MONATSHEFTE FUR CHEMIE | 2010年 / 141卷 / 01期
关键词
Dielectric properties; Self-association; Cyclohexylsulfamic acid; Dioxane solution; VOLUMETRIC PROPERTIES; AQUEOUS-SOLUTIONS;
D O I
10.1007/s00706-009-0228-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The density, refractive index, and electrical permittivity of cyclohexylsulfamic acid in 1,4-dioxane solutions were measured at 298.15 K. The limiting apparent specific volume, refraction, and polarization were calculated from the experimental data. The electrical dipole moment of cyclohexylsulfamic acid was estimated using the Debye, Onsager, and Kirkwood equations. The dipole association of cyclohexylsulfamic acid was treated with the assumption that the dipole moment of dimeric species is zero. The dimerization constant and dipole moment of monomeric species were evaluated.
引用
收藏
页码:23 / 30
页数:8
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