Modification of structure and properties of well-dispersed dendrimer coated multi-walled carbon nanotube reinforced polyester nanocomposites

被引:24
作者
Alam, A. K. M. Moshiul [1 ,2 ]
Beg, M. D. H. [1 ]
Yunus, R. M. [1 ]
Bijarimi, Mohd [1 ]
Mina, M. F. [3 ]
Maria, K. H. [4 ]
Mieno, T. [4 ]
机构
[1] Univ Malaysia Pahang, Fac Chem & Nat Resources Engn, Gambang 26300, Kuantan, Malaysia
[2] Bangladesh Atom Energy Commiss, Inst Radiat & Polymer Technol, Dhaka, Bangladesh
[3] Bangladesh Univ Engn & Technol, Dept Phys, Dhaka 1000, Bangladesh
[4] Shizuoka Univ, Grad Sch Sci & Technol, Shizuoka 422, Japan
关键词
Dendrimer; Nanocomposite; Rheology; Microstructure; Fracture morphology; UNSATURATED POLYESTER; RAMAN-SPECTROSCOPY; HYPERBRANCHED POLYMERS; THERMAL-DECOMPOSITION; MECHANICAL-PROPERTIES; SURFACE MODIFICATION; COMPOSITES; BEHAVIOR; OXIDATION; RESINS;
D O I
10.1016/j.polymertesting.2018.04.005
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This work reveals the structure and properties of dendrimer coated multiwall carbon nanotube (DMWCNT) reinforced unsaturated polyester resin (UPR) nanocomposite. Rheology, as well as the shear thinning behavior of nanosuspension exhibits the dispersion of DMWCNT in UPR matrix. The Raman spectra of DMWCNT-UPR nanocomposites along with the Fourier-transform infrared (FTIR) spectra of DMWCNT and DMWCNT-UPR nanocomposites indicate the interaction between DMWCNT and UPR in the nanocomposite system. Additionally, the surface morphology of DMWCNT and DMWCNT-UPR nanocomposites reveals well dispersion of DMWCNT in DMWCNT-UPR nanocomposites. X-ray diffraction (XRD) profile demonstrates structural properties of pristine UPR and nanocomposites. The Transmission Electron micrograph and Field Emission Scanning Electron micrograph show the fractured surface morphologies of DMWCNT-UPR nanocomposites. Comparative stress-strain behavior shows the deformation mechanism of DMWCNT-UPR nanocomposites.
引用
收藏
页码:116 / 125
页数:10
相关论文
共 45 条
[1]   Cure behavior of epoxy/MWCNT nanocomposites: The effect of nanotube surface modification [J].
Abdalla, Mohamed ;
Dean, Derrick ;
Robinson, Pamela ;
Nyairo, Elijah .
POLYMER, 2008, 49 (15) :3310-3317
[2]   The effect of interfacial chemistry on molecular mobility and morphology of multiwalled carbon nanotubes epoxy nanocomposite [J].
Abdalla, Mohamed ;
Dean, Derrick ;
Adibempe, David ;
Nyairo, Elijah ;
Robinson, Pamela ;
Thompson, Gregory .
POLYMER, 2007, 48 (19) :5662-5670
[3]   Microstructure and Fractography of Multiwalled Carbon Nanotube Reinforced Unsaturated Polyester Nanocomposites [J].
Alam, A. K. M. Moshiul ;
Beg, M. D. H. ;
Yunus, R. M. .
POLYMER COMPOSITES, 2017, 38 :E462-E471
[4]   Evolution of functionalized multi-walled carbon nanotubes by dendritic polymer coating and their anti-scavenging behavior during curing process [J].
Alam, A. K. M. Moshiul ;
Beg, M. D. H. ;
Yunus, R. M. ;
Mina, M. F. ;
Maria, K. H. ;
Mieno, T. .
MATERIALS LETTERS, 2016, 167 :58-60
[5]   Application of the essential work of fracture (EWF) concept for polymers, related blends and composites: A review [J].
Barany, T. ;
Czigany, T. ;
Karger-Kocsis, J. .
PROGRESS IN POLYMER SCIENCE, 2010, 35 (10) :1257-1287
[6]   Improvement of interaction between pre-dispersed multiwalled carbon nanotubes and unsaturated polyester resin [J].
Beg, M. D. H. ;
Alam, A. K. M. Moshiul ;
Yunus, R. M. ;
Mina, M. F. .
JOURNAL OF NANOPARTICLE RESEARCH, 2015, 17 (01)
[7]   Thermogravimetric analysis of the oxidation of multiwalled carbon nanotubes: Evidence for the role of defect sites in carbon nanotube chemistry [J].
Bom, D ;
Andrews, R ;
Jacques, D ;
Anthony, J ;
Chen, BL ;
Meier, MS ;
Selegue, JP .
NANO LETTERS, 2002, 2 (06) :615-619
[8]   Noncovalent interactions of molecules with single walled carbon nanotubes [J].
Britz, David A. ;
Khlobystov, Andrei N. .
CHEMICAL SOCIETY REVIEWS, 2006, 35 (07) :637-659
[9]   Dendrimers and nanotubes: a fruitful association [J].
Caminade, Anne-Marie ;
Majoral, Jean-Pierre .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (06) :2034-2047
[10]   Control of shrinkage and residual styrene of unsaturated polyester resins cured at low temperatures: I. Effect of curing agents [J].
Cao, X ;
Lee, LJ .
POLYMER, 2003, 44 (06) :1893-1902