Cooperative carbon monoxide to formyl reduction at a trifunctional PBB frustrated Lewis pair

被引：26

作者：

Wang, Long ^{[1
]}

Zhang, Senwang ^{[1
]}

Hasegawa, Yasuharu ^{[1
]}

Daniliuc, Constantin G. ^{[1
]}

Kehr, Gerald ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 40期

基金：

欧洲研究理事会;

关键词：

CATALYTIC-REDUCTION; BORINE CARBONYL; CO2; DIOXIDE; BORANE; ACTIVATION; CHEMISTRY; ACID; COMPLEXES; HYDROGENATION;

D O I：

10.1039/c7cc02214j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Twofold hydroboration of the bulky Mes*P(vinyl) 2 phosphane with Piers' borane [HB(C6F5) 2] followed by C6F5/H exchange with 9-BBN generated a reactive P/B/BH FLP structure that cleanly reduced carbon monoxide at the trifunctional frustrated Lewis pair framework to the [B]-formyl stage.Twofold hydroboration of the bulky Mes*P(vinyl) 2 phosphane with Piers' borane [HB(C6F5) 2] followed by C6F5/H exchange with 9-BBN generated a reactive P/B/BH FLP structure that cleanly reduced carbon monoxide at the trifunctional frustrated Lewis pair framework to the [B]-formyl stage.

引用

页码：5499 / 5502

页数：4

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