Poly[[copper(II)-di-μ-5-aminoisophthalato(1-)-κ4N:O] monohydrate]

被引：15

作者：

Liao, QX ^{[1
]}

Li, ZJ ^{[1
]}

Zhang, J ^{[1
]}

Kang, Y ^{[1
]}

Dai, YM ^{[1
]}

Yao, YG ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104020426

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, {[Cu(C8H6NO4)(2)] . H2O}(n), was prepared by the hydrothermal assembly of 5-aminoisophthalic acid with copper nitrate. Single-crystal X-ray analysis shows that it has a two-dimensional layer coordination framework, in which the unique Cu atom lies on an inversion centre and adopts a square-planar geometry, coordinated to two N and two O atoms from symmetry-related ligands. The water molecule lies on a twofold axis and there are hydrogen-bonding interactions between the layers.

引用

页码：M509 / M511

页数：3

共 20 条

[1]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[2]

2-Z

[3] Co-ordination polymers containing square grids of dimension 15 x 15 Å [J].