FTIR study of a silver-thiourea complex generated in argon and nitrogen cryogenic matrices

被引：13

作者：

Cesaro, SN ^{[1
]}

机构：

[1] Univ La Sapienza, Dipartimento Chim, Ctr Studio Termodinam Chim Alte Temp, Rome, Italy

来源：

VIBRATIONAL SPECTROSCOPY | 1998年 / 16卷 / 01期

关键词：

FTIR; silver-thiourea; argon; nitrogen;

D O I：

10.1016/S0924-2031(97)00042-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

FTIR analysis of Ar and N-2 cryogenic matrices doped with thiourea and silver atoms show the generation of a sulfur coordinated complex, which has most likely the Ag[CS(NH2)(2)] formula in view of the experimental conditions used. Frequency shifts are discussed and compared to those observed for thiourea adsorbed on rough silver surface. (C) 1998 Elsevier Science B.V.

引用

页码：55 / 59

页数：5

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