Synthesis of conjugated polymers using aryl-bromides via Cu-catalyzed direct arylation polymerization (Cu-DArP)

被引：15

作者：

Ye, Liwei ^{[1
,2
]}

Pankow, Robert M. ^{[1
,2
]}

Schmitt, Alexander ^{[1
,2
]}

Thompson, Barry C. ^{[1
,2
]}

机构：

[1] Univ Southern Calif, Dept Chem, Los Angeles, CA 90089 USA

[2] Univ Southern Calif, Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA

来源：

POLYMER CHEMISTRY | 2019年 / 10卷 / 48期

基金：

美国国家科学基金会;

关键词：

SEMICONDUCTING POLYMERS; GREEN;

D O I：

10.1039/c9py01478k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Initial reports on the novel Cu-catalyzed direct arylation polymerization (Cu-DArP) stated that it required the use of aryl iodides. Herein, we report the first Cu-DArP methodology using more accessible and practical aryl-bromides with catalytic Cu, leading to a range of conjugated polymers with good molecular weights (up to 17.3 kDa) and an undetectable level of defects.

引用

页码：6545 / 6550

页数：6

共 50 条

[1] An Efficient Precatalyst Approach for the Synthesis of Thiazole-Containing Conjugated Polymers via Cu-Catalyzed Direct Arylation Polymerization (Cu-DArP)
Ye, Liwei
Schmitt, Alexander
Pankow, Robert M.
Thompson, Barry C.
ACS MACRO LETTERS, 2020, 9 (10) : 1446 - 1451
[2] Sustainable Synthesis of a Fluorinated Arylene Conjugated Polymer via Cu-Catalyzed Direct Arylation Polymerization (DArP)
Pankow, Robert M.
Ye, Liwei
Thompson, Barry C.
ACS MACRO LETTERS, 2018, 7 (10) : 1232 - 1236
[3] Sustainable methods for the preparation of conjugated polymers using direct arylation polymerization (DArP)
Pankow, Robert
Thompson, Barry
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
[4] Approaches for improving the sustainability of conjugated polymer synthesis using direct arylation polymerization (DArP)
Pankow, Robert M.
Thompson, Barry C.
POLYMER CHEMISTRY, 2020, 11 (03) : 630 - 640
[5] An environmentally benign procedure for the Cu-catalyzed cyanation of aryl bromides
Schareina, T
Zapf, A
Beller, M
TETRAHEDRON LETTERS, 2005, 46 (15) : 2585 - 2588
[6] Cu-Catalyzed Direct Arylation of Benzothiazoles with Diaryliodonium Salts
Li, Huaigui
Yang, Peng
Xu, Zheng
Du, Zhengyin
Fu, Ying
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (08) : 2476 - 2482
[7] Cu-catalyzed asymmetric allylic arylation with aryl lithium reagents
Guduguntla, Sureshbabu
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
[8] Influence of an ester directing-group on defect formation in the synthesis of conjugated polymers via direct arylation polymerization (DArP) using sustainable solvents
Pankow, Robert M.
Ye, Liwei
Thompson, Barry C.
POLYMER CHEMISTRY, 2019, 10 (33) : 4561 - 4572
[9] Cu-Catalyzed Coupling Reactions of Sulfonamides with (Hetero)Aryl Chlorides/Bromides
Li, Qiaoli
Xu, Lanting
Ma, Dawei
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (43)
[10] Synthesis of Triarylphosphines via Cu-Catalyzed Coupling of Aryl Halides and Acylphosphines
Xu, Minghui
Zhu, Zhengping
Yi, Haojie
Zhu, Hong
Wang, Zhiqian
SYNTHESIS-STUTTGART, 2023, 55 (16): : 2586 - 2594

← 1 2 3 4 5 →