Supercritical-CO2 corrosion behavior of alumina- and chromia-forming heat resistant alloys with Ti

被引:20
作者
Subramanian, Gokul Obulan [1 ]
Kim, Sung Hwan [1 ]
Chen, Junjie [1 ]
Jang, Changheui [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Daejeon 34141, South Korea
基金
新加坡国家研究基金会;
关键词
Heat resistant alloy; Alumina-forming alloy; Supercritical carbon dioxide; Al2O3; Pre-oxidation; CO2 BRAYTON CYCLES; STAINLESS-STEEL; CARBURIZATION BEHAVIOR; TEMPERATURE OXIDATION; CREEP-RESISTANT; CR ALLOYS; TEMPLATE;
D O I
10.1016/j.corsci.2021.109531
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Short-term corrosion behavior of the alumina- and chromia-forming Fe-Ni-based heat resistant alloys with Ti for gamma'-Ni-3(Al,Ti) precipitation were evaluated in supercritical-CO2 (sCO(2)) environment at 650 degrees C and 20 MPa for 457 h. The corrosion test showed development of thinner oxides with some occasional Fe-rich oxide nodules in alumina-forming alloy A (16Cr-4.5Al-3Ti). However, chromia-forming alloy C (20Cr-2Al-2Ti) exhibited several occurrences of Fe-rich oxide nodules and spallation of thinner oxides. Meanwhile, the pre-oxidation treatment resulted in improved corrosion resistance in sCO(2) environment by preventing the Fe-rich oxide nodule formation and oxide spallation, especially for alloy A with formation of alpha-Al2O3.
引用
收藏
页数:15
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