Trimetallic Layered Hydroxide Anchored on a Bimetallic NiCo-MOFD erivative as a Self-Supporting Electrode Material for Boosting Supercapacitance

被引:23
作者
Li, Shaobin [1 ]
Yu, Tingting [1 ]
Li, Fengbo [3 ]
Chen, Tingting [1 ]
Zhang, Li [1 ]
Wang, Guangning [2 ]
Xin, Jianjiao [3 ]
Zhang, Deqing [1 ]
机构
[1] Qiqihar Univ, Coll Mat Sci & Engn, Key Lab Polymer Composite Mat Heilongjiang Prov, Qiqihar 161006, Peoples R China
[2] Harbin Normal Univ, Sch Phys & Elect Engn, Minist Educ, Key Lab Photon & Elect Bandgap Mat, Harbin 150025, Peoples R China
[3] Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Peoples R China
关键词
METAL-ORGANIC FRAMEWORKS; HIGH-PERFORMANCE; LDH COMPOSITE; NICKEL FOAM; CONSTRUCTION; ARRAY; FABRICATION; NANOARRAYS; NANOSHEETS; NANOTUBES;
D O I
10.1021/acs.energyfuels.2c00813
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The electrochemical properties of the layered double hydroxides (LDHs) are influenced by both composition and nanostructure to a great extent. In this work, a novel composite electrode material NiCoC/O-NiCoAl LDH was synthesized using a bimetallic NiCo-metal-organic framework (MOF) as the precursor. The composite electrode material NiCoC/O-NiCoAl LDH exhibited a three-dimensional (3D) nanoflower-like structure and multiple surface element state and was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), trans-mission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) measurements. The electrode material exhibited an outstanding specific capacitance of 2400 F g-1at a current density of 1 A g-1. The fabricated aqueous hybrid supercapacitor NiCoC/O-NiCoAl LDH//AC exhibited an energy density of 80 W h kg-1at a power density of 750 W kg-1.Inaddition, the fabricated device exhibited excellent cycling stability and durability. The present work provides a suggestive contribution to the design and synthesis of 3D NiCoC/O-NiCoAl LDH as well as their potential applications in green energy storage.
引用
收藏
页码:5492 / 5501
页数:10
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