A pulsed supersonic entrainment reactor for the rational preparation of cold ionic complexes

被引：90

作者：

Robertson, WH ^{[1
]}

Kelley, JA ^{[1
]}

Johnson, MA ^{[1
]}

机构：

[1] Yale Dept Chem, Sterling Chem Lab, New Haven, CT 06520 USA

来源：

REVIEW OF SCIENTIFIC INSTRUMENTS | 2000年 / 71卷 / 12期

关键词：

D O I：

10.1063/1.1326931

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

We describe an ion source for the efficient preparation of cold ion-molecule complexes, X-.M. The method relies on condensation of solvent molecules, M, onto argon-solvated ions, X-.Ar-m, where the X-.Ar-m species are formed in a primary expansion and the molecular partner, M, is interfaced to this flow in the hydrodynamic region by supersonic entrainment. This hybrid "supersonic afterglow" reactor provides a clean synthetic approach for both bare and argon-solvated complexes, where the latter are particularly useful since their structures can be characterized by "nanomatrix" infrared predissociation spectroscopy. (C) 2000 American Institute of Physics. [S0034- 6748(00)00801-2].

引用

页码：4431 / 4434

页数：4

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