Growth of Cadmium Nanocrystals

被引:6
|
作者
Adams, Laura L. A. [1 ]
Sweeney, William R. [1 ]
Jaeger, Heinrich M. [1 ]
机构
[1] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY C | 2010年 / 114卷 / 14期
关键词
COLLOIDAL CADMIUM; NANOWIRES;
D O I
10.1021/jp911820s
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cadmium nanocrystals were synthesized by reduction of cadmium acetate in three different mediums Transmission electron microscopy studies of the reaction products revealed a range of different shapes depending on the ratio of capping and reducing agents, the addition Lime of these agents, and the duration and temperature of the reaction X-ray results confirmed the crystallinity of these faceted structures with the dominant crystal facet along the (002) direction. Optical absorption spectra showed either one or two plasmon resonances in the ultraviolet (lambda = 280 nm and/or 235 nm) depending on the diameter of the spherical particles in solution Finally, cadmium nanocrystals were converted to cadmium sulfide by addition of thiourea, TEX.
引用
收藏
页码:6304 / 6310
页数:7
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