5"-benzylidene-1′,1"-dimethyl-4′-phenylacenapthene-2-spiro-2′-pyrrolidine-3′-spiro-3"-piperidine-1,4"-dione

被引：4

作者：

Aravindan, PG

Selvanayagam, S

Velmurugan, D

Ravikumar, K

Sridhar, G

Raghunathan, R

机构：

[1] Univ Madras, Dept Crystallog & Biophys, Madras 600025, Tamil Nadu, India

[2] Indian Inst Chem Technol, Lab Xray Crystallog, Hyderabad 500007, Andhra Pradesh, India

[3] Univ Madras, Dept Organ Chem, Madras 600025, Tamil Nadu, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S160053680402690X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C34H30N2O2, the pyrrolidine and piperidinone rings each adopt a half-chair conformation. The dihedral angle between the two phenyl-ring substituents is 70.4 (1)degrees. Intramolecular C-H...O hydrogen bonds are observed in the crystal structure. In addition to these interactions, C-H...pi interactions also play a role in stabilizing the crystal structure.

引用

页码：O2149 / O2151

页数：3

共 17 条

[1] PATTERNS IN HYDROGEN BONDING - FUNCTIONALITY AND GRAPH SET ANALYSIS IN CRYSTALS
BERNSTEIN, J
DAVIS, RE
SHIMONI, L
CHANG, NL
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (15) : 1555 - 1573
[2] SYNTHESIS AND ANTICONVULSANT ACTIVITY OF SOME SUBSTITUTED LACTAMS AND AMIDES
BROUILLETTE, WJ
GRUNEWALD, GL
[J]. JOURNAL OF MEDICINAL CHEMISTRY, 1984, 27 (02) : 202 - 206
[3] *BRUK AXS INC, 2001, SMART VERS 5 625
[4] *BRUK AXS INC, 2001, SAINT VERS 6 28A
[5] Azomethine ylide cycloaddition/reductive heterocyclization approach to oxindole alkaloids: Asymmetric synthesis of (-)-horsfiline
Cravotto, G
Giovenzana, GB
Pilati, T
Sisti, M
Palmisano, G
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (25) : 8447 - 8453
[6] GENERAL DEFINITION OF RING PUCKERING COORDINATES
CREMER, D
POPLE, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) : 1354 - 1358
[7] Stereoselective reduction of chiral trans-3-acetyl-4-alkylpyrrolidin-2-ones
Galeazzi, R
Geremia, S
Mobbili, G
Orena, M
[J]. TETRAHEDRON-ASYMMETRY, 1999, 10 (03) : 587 - 605
[8] AZOLES 28 STRUCTURE OF THE MOLECULAR-COMPLEX OF 3,5-DINITROINDAZOLE WITH PYRROLIDINE (1/1)
GZELLA, A
WRZECIONO, U
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 2107 - 2109
[9] 3-Benzylidene-1′-methyl-4′-phenylcyclohexanespiro3′-pyrrolidine-2′-spiro-3"-indoline-2,2"-dione
Jeyabharathi, A
Ponnuswamy, MN
Raj, AA
Raghunathan, R
Razak, IA
Usman, A
Chantrapromma, S
Fun, HK
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : o901 - O903
[10] RING ASYMMETRY PARAMETERS FROM OUT-OF-PLANE ATOMIC DISPLACEMENTS
NARDELLI, M
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (AUG) : 1141 - 1142

← 1 2 →