Phosphorescent 2-, 3-and 4-coordinate cyclic (alkyl)(amino) carbene (CAAC) Cu(I) complexes

被引：67
|
作者：
Hamze, Rasha [1 ]
Jazzar, Rodolphe [2 ]
Soleilhavoup, Michele [2 ]
Djurovich, Peter I. [1 ]
Bertrand, Guy [2 ]
Thompson, Mark E. [1 ]
机构：
[1] Univ Southern Calif, Dept Chem, Los Angeles, CA 90089 USA
[2] Univ Calif San Diego, Dept Chem, La Jolla, CA 92093 USA
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 64期
关键词：
LIGHT-EMITTING-DIODES; DELAYED FLUORESCENCE; LIGANDS SYNTHESIS; METAL-COMPLEXES; EXCITED-STATE; LUMINESCENCE; CATALYSTS; CLUSTERS;
D O I：
10.1039/c7cc02638b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photophysical properties of several Cu(I) complexes coordinated with cyclic (alkyl)(amino) carbene (CAAC) ligands were examined. All the compounds were found to be phosphorescent, regardless of whether they are 2-, 3-or 4-coordinated. Aggregate and excimer emission were observed from 2-coordinate CAAC-CuCl derivatives in methylcyclohexane solution. Emission from the complex 4-coordinated with a trispyrazolylborate ligand is red-shifted with respect to both the chloro-derivative and an analogous complex with an NHC ligand.
引用
收藏
页码：9008 / 9011
页数：4
相关论文
共 50 条
  • [1] Phosphorescent 2-, 3-, and 4-coordinate cyclic (alkyl)(amino) carbene (CAAC) Cu(I) complexes
    Hamze, Rasha
    Jazzar, Rodolphe
    Soleilhavoup, Michele
    Djurovich, Peter
    Bertrand, Guy
    Thompson, Mark
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [2] Luminescent 3-and 4-coordinate copper carbene complexes
    Thompson, Mark
    Hamze, Rasha
    Djurovich, Peter
    Krylova, Valentina
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [3] Cyclic (Alkyl)(Amino)Carbene (CAAC) Gold(I) Complexes as Chemotherapeutic Agents
    Proetto, Maria T.
    Alexander, Kelsey
    Melaimi, Mohand
    Bertrand, Guy
    Gianneschi, Nathan C.
    CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (11) : 3772 - 3778
  • [4] Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis
    Marx, Vanessa
    Sullivan, Alexandra
    Melaimi, Mohand-Ameziane
    Virgil, Scott
    Bertrand, Guy
    Grubbs, Robert
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [5] Asymmetric cyclic alkyl amino carbene (CAAC) ruthenium complexes as improved catalysts for ethenolysis
    Marx, Vanessa M.
    Melaimi, Mohand
    Grubbs, Robert H.
    Bertrand, Guy
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [6] Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis
    Marx, Vanessa M.
    Sullivan, Alexandra H.
    Melaimi, Mohand
    Virgil, Scott C.
    Keitz, Benjamin K.
    Weinberger, David S.
    Bertrand, Guy
    Grubbs, Robert H.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (06) : 1919 - 1923
  • [7] Photoluminescence of 3-and 4-coordinate platinum(0) phosphine complexes
    Mizumoto, Yoji
    Murao, Mio
    Yamazaki, Yasuomi
    Tsubomura, Taro
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2024, 97 (05)
  • [8] 2-COORDINATE AND 4-COORDINATE GOLD(I) COMPLEXES OF TRIS(2-(DIPHENYLPHOSPHINO)ETHYL)PHOSPHINE
    BALCH, AL
    FUNG, EY
    INORGANIC CHEMISTRY, 1990, 29 (23) : 4764 - 4768
  • [9] Neutral and Cationic Molybdenum Imido Alkylidene Cyclic Alkyl Amino Carbene (CAAC) Complexes for Olefin Metathesis
    Kundu, Koushani
    Musso, Janis V.
    Benedikter, Mathis J.
    Frey, Wolfgang
    Gugeler, Katrin
    Kaestner, Johannes
    Buchmeiser, Michael R.
    CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (52)
  • [10] A Straightforward Access to Cyclic (Alkyl)(amino)carbene Copper (I) Complexes
    Lorkowski, Jan
    Serrato, Melinda R.
    Gembicki, Milan
    Mauduit, Marc
    Bertrand, Guy
    Jazzar, Rodolphe
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 26 (15)
12345