Geopolymer synthesis using silica fume and sodium aluminate

被引:96
作者
Brew, D. R. M.
MacKenzie, K. J. D.
机构
[1] New Zealand Inst Res & Dev, Lower Hutt, New Zealand
[2] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington, New Zealand
关键词
D O I
10.1007/s10853-006-0376-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Monoliths that set rapidly and harden at ambient temperature have been prepared by exploiting sol-gel type condensation reactions between sodium silicate, formed in-situ by alkaline dissolution of silica fume, and a solution of sodium aluminate. Structural characterisation of the product was carried out by XRD, Al-27 and Si-29 MAS NMR spectroscopy) and the samples showed reproducibly good compressive strengths, indicating that the products display all the characteristics of typical aluminosilicate geopolymers.
引用
收藏
页码:3990 / 3993
页数:4
相关论文
共 10 条
[1]   Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers [J].
Barbosa, VFF ;
MacKenzie, KJD ;
Thaumaturgo, C .
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2000, 2 (04) :309-317
[2]   Fire-resistant geopolymer produced by granulated blast furnace slag [J].
Cheng, TW ;
Chiu, JP .
MINERALS ENGINEERING, 2003, 16 (03) :205-210
[3]   GEOPOLYMERS - INORGANIC POLYMERIC NEW MATERIALS [J].
DAVIDOVITS, J .
JOURNAL OF THERMAL ANALYSIS, 1991, 37 (08) :1633-1656
[4]   The composition range of aluminosilicate geopolymers [J].
Fletcher, RA ;
MacKenzie, KJD ;
Nicholson, CL ;
Shimada, S .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2005, 25 (09) :1471-1477
[5]  
MacKenzie KJD, 2003, CERAM TRANS, V153, P175
[6]  
MACKENZIE KJD, 2005, UNPUB J MAT SCI
[7]  
PUYAM SS, 2005, MAT SCI ENG A-STRUCT, V396, P392
[8]   Utilisation of fly ash in a geopolymeric material [J].
Swanepoel, JC ;
Strydom, CA .
APPLIED GEOCHEMISTRY, 2002, 17 (08) :1143-1148
[9]  
Taylor H., 1997, CEMENT CHEM, V2
[10]   The characterisation of source materials in fly ash-based geopolymers [J].
van Jaarsveld, JGS ;
van Deventer, JSJ ;
Lukey, GC .
MATERIALS LETTERS, 2003, 57 (07) :1272-1280