Solid-phase synthesis of protonated nitrogen-containing heterocyclic compounds with the boron cluster anions starting from [Eu(H2O)9]2[B10Cl10]3: Synthesis, structure, and thermal properties of (HL)2[B10Cl10] (L=7-amino-4-methylcoumarin or 1-ethyl-2-(4-methoxyphenyl) azobenzimidazole)

被引：7
作者：
Malinina, Elena A. [1 ]
Korolenko, Svetlana E. [1 ]
Kubasov, Alexey S. [1 ]
Buzanov, Grigorii A. [1 ]
Golubev, Alexey, V [1 ]
Goeva, Lyudmila, V [1 ]
Simonenko, Nikolay P. [1 ]
Avdeeva, Varvara V. [1 ]
Kuznetsov, Nikolay T. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 1119991, Russia
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2021年 / 302卷
关键词：
Decachloro-closo-decaborate anion; X-ray diffraction; Thermal properties; Azaheterocyclic ligands; CLOSO-DECABORATE ANION; N-DONOR LIGANDS; IONIC LIQUIDS; CL-35; NQR; COMPLEXATION; CHEMISTRY; SUBSTITUTION; DERIVATIVES; SPECTRA; BORANES;
D O I：
10.1016/j.jssc.2021.122413
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The paper proposes a new method for the synthesis of salts of a perchlorinated derivative of the decahydro-closodecaborate anion with neutral N-containing organic bases L-1 and L-2 starting from previously prepared europium precursor [Eu(H2O)(9)](2)[B10Cl10](3). Compound [Eu(H2O)(9)](2)[B10Cl10](3) was first synthesized and characterized by elemental analysis, X-ray powder diffraction, IR spectroscopy and its thermal properties were studied by TGA. The protonation of organic bases L was carried out in the solid phase in the presence of precursor [Eu(H2O)(9)](2)[B10Cl10](3). For comparison, the reaction was carried out in solution: in the CH3CN/CF3COOH system and in an aqueous solution of (H3O)(2)[B10Cl10] with pronounced acidic properties. The influence of reaction conditions on the composition and structure of the final products was analyzed. Salts of the composition (HL)(2)[B10Cl10] (L is 1-ethyl-2-(4-methoxyphenyl)azobenzimidazole (L1) and 7-amino-4-methylcoumarin (L-2)) and (HL2)(H9O4) [B10Cl10] were synthesized and characterized by X-ray diffraction. The thermal properties of the obtained salts and ligand L1 (C16H16N4O) were studied in air in the temperature range 20-600 degrees C.
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页数：11
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共 60 条
  • [1] Hydrogen-bonded superstructures of a small host molecule and lanthanide aquo ions
    Ahmad, R
    Dix, I
    Hardie, MJ
    [J]. INORGANIC CHEMISTRY, 2003, 42 (07) : 2182 - 2184
  • [2] GEOMETRY OF NONAAQUALANTHANOID(3+) COMPLEX IN SOLID BROMATES AND ETHYL SULFATES
    ALBERTSSON, J
    ELDING, I
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (MAY13): : 1460 - 1469
  • [3] Thiocarbamide Derivatives of Europium, Holmium, and Erbium Iodides: Synthesis and Structures
    Antonenko, T. A.
    Alikberova, L. Yu
    Albov, D. V.
    Rukk, N. S.
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (10) : 785 - 790
  • [4] Structural Diversity of Cationic Copper(II) Complexes with Neutral Nitrogen-Containing Organic Ligands in Compounds with Boron Cluster Anions and Their Derivatives (Review)
    Avdeeva, V. V.
    Malinina, E. A.
    Zhizhin, K. Yu.
    Kuznetsov, N. T.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 65 (04) : 514 - 534
  • [5] Structural Diversity of Dimer Clusters Based on the Octadecahydro-Eicosaborate Anion
    Avdeeva, V. V.
    Malinina, E. A.
    Zhizhin, K. Yu.
    Bernhardt, E.
    Kuznetsov, N. T.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 60 (05) : 692 - 712
  • [6] Boron Cluster Anions [B10X10]2- (X = H, Cl) in Manganese(II) Complexation with 2,2'-Bipyridyl
    Avdeeva, V. V.
    Vologzhanina, A. V.
    Malinina, E. A.
    Zhizhin, K. Yu
    Kuznetsov, N. T.
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (04) : 295 - 300
  • [7] Coordination chemistry of iron triad metals with organic N-donor ligands and boron cluster anions [B10H10]2-, [B12H12]2-, and [B10Cl10]2-: Complexation and accompanying processes
    Avdeeva, V. V.
    Malinina, E. A.
    Kuznetsov, N. T.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2017, 62 (13) : 1673 - 1702
  • [8] Decachloro-closo-decaborate anion in copper(II) complexation reactions with N-donor ligands: 35Cl NQR and X-ray studies
    Avdeeva, V. V.
    Kravchenko, E. A.
    Gippius, A. A.
    Vologzhanina, A. V.
    Malinina, E. A.
    Zhurenko, S. V.
    Buzanov, G. A.
    Kuznetsov, N. T.
    [J]. POLYHEDRON, 2017, 127 : 238 - 247
  • [9] Synthesis and structure of [NiL6][B10H10] (L = DMF or DMSO) as precursors for solid-phase synthesis of nickel(II) coordination compounds
    Avdeeva, V. V.
    Polyakova, I. N.
    Goeva, L. V.
    Buzanov, G. A.
    Malinina, E. A.
    Kuznetsov, N. T.
    [J]. INORGANICA CHIMICA ACTA, 2016, 451 : 129 - 134
  • [10] Redox, complexation, and substitution reactions in [Cu2B10H10]-2,2′-bipyridylamine-CH3CN system
    Avdeeva, V. V.
    Dziova, A. E.
    Polyakova, I. N.
    Goeva, L. V.
    Malinina, E. A.
    Kuznetsov, N. T.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (06) : 657 - 663
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