Hydrothermal syntheses and photocatalytic performance of three Mn-based coordination complexes constructed from 1,10-phenanthroline and polycarboxylic acids

被引：10

作者：

Wang, Chong-Chen ^{[1
,2
]}

Gao, Fang ^{[1
]}

Guo, Xin-Xing ^{[1
]}

Jing, Huan-Ping ^{[1
]}

Wang, Peng ^{[1
]}

Gao, Shi-Jie ^{[1
]}

机构：

[1] Minist Educ, Key Lab Urban Stormwater Syst & Water Environm, Beijing 100044, Peoples R China

[2] Beijing Univ Civil Engn & Architecture, Beijing Engn Res Ctr Sustainable Urban Sewage Sys, Beijing 100044, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2016年 / 41卷 / 04期

基金：

中国国家自然科学基金; 北京市自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; CARBOXYLIC-ACIDS; LUMINESCENT PROPERTIES; SILVER(I) COMPLEXES; LIGANDS SYNTHESES; SERIES; POLYMER; DEGRADATION; REDUCTION;

D O I：

10.1007/s11243-016-0033-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three coordination complexes based on manganese, namely Mn(phen)(5-Br-ipa) (1), Mn(phen)(5-NO2-ipa) (2), and [Mn(phen)(2)(3,4-H(2)dczpb)]center dot H2O (3) (phen = 1,10-phenanthroline; 5-Br-ipa = 5-bromoisophthalic acid; 5-NO2-ipa = 5-nitroisophthalic acid; 3,4-H(4)dczpb = 3,4-dicarboxyl-(3',4'-dicarboxylazophenyl)benzene), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis, and UV-Vis diffuse reflection spectroscopy. The photocatalytic efficiencies of the complexes for the decomposition of methylene blue under UV irradiation were also investigated. These complexes show 2D sheet, 1D chain and 0D discrete structures due to the different coordination environments of the Mn(II) centers and the number of phen ligands.

引用

页码：375 / 385

页数：11

共 48 条

[41] Highly Thermostable One-Dimensional Lanthanide(III) Coordination Polymers Constructed from Benzimidazole-5,6-dicarboxylic Acid and 1,10-Phenanthroline: Synthesis, Structure, and Tunable White-Light Emission [J].

Ma, Xue ;

Li, Xia ;

Cha, Yu-E ;

Jin, Lin-Pei .

CRYSTAL GROWTH & DESIGN, 2012, 12 (11) :5227-5232

[42] Two novel copper(II) complexes constructed from dicarboxylate ligands with different spacer lengths and 2-phenylimidazo[4,5-f]1,10-phenanthroline (PIP): Synthesis, structures and properties [J].

Wang, X. -L. ;

Chen, Yongqiang ;

Liu, Guocheng ;

Lin, Hongyan ;

Zhang, Jinxia .

SOLID STATE SCIENCES, 2009, 11 (09) :1567-1571

[43] Syntheses and structures of 1d coordination polymers based on cluster anions [Re4Te4(CN)12]4- and cationic Ln3+ (Ln = La, Gd) complexes with 1,10-phenanthroline [J].

Gayfulin, Ya. M. ;

Kuratieva, N. V. ;

Litvinova, Yu. M. ;

Mironov, Yu. V. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2016, 42 (07) :423-428

[44] Syntheses, crystal structures, and luminescence of two lanthanide coordination polymers based on 5-(3′,4′-bis(tetrazol-5"-yl)phenoxy)isophthalic acid and 1,10-phenanthroline [J].

Chen, Xiaoli ;

Li, Congcong ;

Ai, Fengfeng ;

Qu, Xu ;

Liu, Kang .

JOURNAL OF MOLECULAR STRUCTURE, 2017, 1133 :369-373

[45] Synthesis, Structure, and Surface Photo-electric Properties of a New Zn(II) Coordination Complex Constructed from 2-(1H-benzotriazol-1-yl)acetic Acid and 1,10-Phenanthroline Ligands [J].

Li Jia-Ming ;

Shi Zhong-Feng ;

He Kun-Huan .

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35 (01) :135-142

[46] Syntheses, structures, and photoluminescence of a series of d10 coordination complexes from N,N′-bidentate imidazo[4,5-f][1,10]phenanthroline and benzene-1,3,5-tricarboxylic acid [J].

Che, Guang-Bo ;

Wang, Shan-Shan ;

Zha, Xiao-Lin ;

Li, Xiu-Ying ;

Liu, Chun-Bo ;

Zhang, Xing-Jing ;

Xu, Zhan-Lin ;

Wang, Qing-Wei .

INORGANICA CHIMICA ACTA, 2013, 394 :481-487

[47] Three new cadmium(II) coordination compounds based on 2-(pyridin-3-yl)-1H-imidazo[4,5-f][1,10] phenanthroline: syntheses, structures and luminescence [J].

Xu, Bing ;

Han, Zhong-Xi ;

Hu, Huai-Ming .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2020, 75 (9-10) :843-849

[48] Bi- and trinuclear cobalt based coordination polymers constructed from aromatic polycarboxylic acids and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene: Crystal structure and magnetic properties [J].

Xing, Xiaoyan ;

Song, Xueyan ;

Yang, Peipei ;

Liu, Ruina ;

Li, Licun ;

Liao, Daizheng .

JOURNAL OF MOLECULAR STRUCTURE, 2010, 967 (1-3) :196-200

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