Hydrothermal syntheses and photocatalytic performance of three Mn-based coordination complexes constructed from 1,10-phenanthroline and polycarboxylic acids

被引：10
作者：
Wang, Chong-Chen [1 ,2 ]
Gao, Fang [1 ]
Guo, Xin-Xing [1 ]
Jing, Huan-Ping [1 ]
Wang, Peng [1 ]
Gao, Shi-Jie [1 ]
机构：
[1] Minist Educ, Key Lab Urban Stormwater Syst & Water Environm, Beijing 100044, Peoples R China
[2] Beijing Univ Civil Engn & Architecture, Beijing Engn Res Ctr Sustainable Urban Sewage Sys, Beijing 100044, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2016年 / 41卷 / 04期
基金：
中国国家自然科学基金; 北京市自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; CARBOXYLIC-ACIDS; LUMINESCENT PROPERTIES; SILVER(I) COMPLEXES; LIGANDS SYNTHESES; SERIES; POLYMER; DEGRADATION; REDUCTION;
D O I：
10.1007/s11243-016-0033-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three coordination complexes based on manganese, namely Mn(phen)(5-Br-ipa) (1), Mn(phen)(5-NO2-ipa) (2), and [Mn(phen)(2)(3,4-H(2)dczpb)]center dot H2O (3) (phen = 1,10-phenanthroline; 5-Br-ipa = 5-bromoisophthalic acid; 5-NO2-ipa = 5-nitroisophthalic acid; 3,4-H(4)dczpb = 3,4-dicarboxyl-(3',4'-dicarboxylazophenyl)benzene), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis, and UV-Vis diffuse reflection spectroscopy. The photocatalytic efficiencies of the complexes for the decomposition of methylene blue under UV irradiation were also investigated. These complexes show 2D sheet, 1D chain and 0D discrete structures due to the different coordination environments of the Mn(II) centers and the number of phen ligands.
引用
收藏
页码：375 / 385
页数：11
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