Palladium Catalysts Based on Mesoporous Organic Materials in Semihydrogenation of Alkynes

被引：15

作者：

Boronoev, Maksim P. ^{[1
]}

Zolotukhina, Anna V. ^{[1
]}

Ignatyeva, Victoria I. ^{[1
]}

Terenina, Maria V. ^{[1
]}

Maximov, Anton L. ^{[1
,2
]}

Karakhanov, Eduard A. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Petr Chem & Organ Catalysis, Moscow 119991, Russia

[2] Inst Petrochem Synth RAS, Moscow 119991, Russia

来源：

MACROMOLECULAR SYMPOSIA | 2016年 / 363卷 / 01期

关键词：

catalysis; dendrimers; hydrogenation; mesoporous polymers; nanoparticles; palladium; ENCAPSULATED METAL NANOPARTICLES; SELECTIVE HYDROGENATION; PD-NANOPARTICLES; COMPOSITES; POLYMERS; LIQUID; MCM-41;

D O I：

10.1002/masy.201500184

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Catalyst based on palladium nanoparticles and poly(propyleneimine) (PPI) dendrimers immobilized on mesoporous phenol-formaldehyde support was synthesized. Catalytic characteristics were evaluated in the hydrogenation of 1-octyne, 4-octyne, and 1-hexyne. High selectivity for alkenes (up to 99%) was achieved. Synthesized hybrid catalyst can be recycled without a loss of activity and additional regeneration.

引用

页码：57 / 63

页数：7

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