Light-Driven Hydrogen Generation: Efficient Iron-Based Water Reduction Catalysts

被引：149

作者：

Gaertner, Felix ^{[1
]}

Sundararaju, Basker ^{[2
]}

Surkus, Annette-Enrica ^{[1
]}

Boddien, Albert ^{[1
]}

Loges, Bjoern ^{[1
]}

Junge, Henrik ^{[1
]}

Dixneuf, Pierre H. ^{[2
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

[2] Univ Rennes, Lab Catalyse & Organometall, Inst Sci Chim Rennes, CNRS 6226, Rennes, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 52期

关键词：

energy conversion; homogeneous catalysis; iron; photochemistry; water splitting; VISIBLE-LIGHT; HOMOGENEOUS SYSTEM; MOLECULAR-HYDROGEN; ELECTRON-TRANSFER; AQUEOUS-SOLUTIONS; METAL-COMPLEXES; PHOTOCATALYST; EVOLUTION; PHOTOGENERATION; IRRADIATION;

D O I：

10.1002/anie.200905115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(figure represented) Let your light shine: A novel state-of-theart system for light-driven proton reduction with iron catalysts was developed (see scheme; SR = sacrificial reagent). It consists of simple iron carbonyl complexes such as [Fe3(CO)12], triethylamine as sacrificial reagent (electron donor), and [Ir(bpy)(ppy)2]PF6 as photosensitizer (PS). High turnover numbers of more than 3000 for the sensitizer and 400 for the iron catalyst are obtained. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9962 / 9965

页数：4

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