Analysis of solar cell cross sections with micro-light beam induced current (μLBIC)

被引:8
作者
Breitwieser, Matthias [1 ]
Heinz, Friedemann D. [1 ]
Buechler, Andreas [1 ]
Kasemann, Martin [2 ]
Schon, Jonas [1 ]
Warta, Wilhelm [1 ]
Schubert, Martin C. [1 ]
机构
[1] Fraunhofer Inst Solar Energy Syst, D-79110 Freiburg, Germany
[2] Univ Freiburg, Dept Microsyst Engn, D-79110 Freiburg, Germany
关键词
mu LBIC; Raman spectroscopy; Micro-characterization; Grain boundary diffusion; Nickel silicide; DIFFUSION; METALLIZATION; SPECTROSCOPY;
D O I
10.1016/j.solmat.2014.05.002
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A highly resolving micro-light beam-induced current (mu LBIC)-system is presented in this work. Based on the laser excitation via an optical microscope, current values can be measured with sub-micron precision. We show, that this non-destructive, light-based approach delivers superior results to a reference electron microscope based electron beam induced current method concerning contrast and robustness towards reflection differences, whereas no vacuum is needed, no charging effects can occur and equal resolution is achieved. mu LBIC allows therefore mapping of pn-junctions at silicon solar cell cross sections. By combination of mu LBIC with other measurement methods in the same setup, such as micro-Raman spectroscopy, complementary microscopic information about material stress or crystallinity and electronic properties at the same region of interest on the sample is revealed. By applying mu LBIC for analyzing silicon solar cross sections, two characterization examples of current technological relevance are presented: enhanced dopant diffusion along grain boundaries between grains with different orientations is quantified and the impact of a nickel silicide spike on local charge collection quality is studied. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:124 / 128
页数:5
相关论文
共 21 条
[1]  
Andreas Buchler, 2014, PHYS STATUS SOLIDI R
[2]  
[Anonymous], 2002, SEMICONDUCTOR DEVICE
[3]   Quick Determination of Copper-Metallization Long-Term Impact on Silicon Solar Cells [J].
Bartsch, J. ;
Mondon, A. ;
Bayer, K. ;
Schetter, C. ;
Hoerteis, M. ;
Glunz, S. W. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (10) :H942-H946
[4]   Highly p-doped regions in silicon solar cells quantitatively analyzed by small angle beveling and micro-Raman spectroscopy [J].
Becker, M. ;
Goesele, U. ;
Hofmann, A. ;
Christiansen, S. .
JOURNAL OF APPLIED PHYSICS, 2009, 106 (07)
[5]   DIFFUSION CHARACTERISTICS OF BORON AND PHOSPHORUS IN POLYCRYSTALLINE SILICON [J].
BUONAQUISTI, AD ;
CARTER, W ;
HOLLOWAY, PH .
THIN SOLID FILMS, 1983, 100 (03) :235-248
[6]   Toroidal crystal spectrometer for time-resolved x-ray absorption diagnostic in dense plasmas [J].
Pisani, F ;
Koenig, M ;
Batani, D ;
Hall, T ;
Desenne, D ;
Bruneau, J ;
Reverdin, C .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1999, 70 (08) :3314-3318
[7]   Quantitative carrier lifetime measurement with micron resolution [J].
Gundel, Paul ;
Heinz, Friedemann D. ;
Schubert, Martin C. ;
Giesecke, Johannes A. ;
Warta, Wilhelm .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (03)
[8]   Micro-photoluminescence spectroscopy on metal precipitates in silicon [J].
Gundel, Paul ;
Schubert, Martin C. ;
Kwapil, Wolfram ;
Schoen, Jonas ;
Reiche, Manfred ;
Savin, Hele ;
Yli-Koski, Marko ;
Sans, Juan Angel ;
Martinez-Criado, Gema ;
Seifert, Winfried ;
Warta, Wilhelm ;
Weber, Eicke R. .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2009, 3 (7-8) :230-232
[9]   INFLUENCE OF DISLOCATIONS ON DIFFUSION KINETICS IN SOLIDS WITH PARTICULAR REFERENCE TO ALKALI HALIDES [J].
HARRISON, LG .
TRANSACTIONS OF THE FARADAY SOCIETY, 1961, 57 (08) :1191-&
[10]   Optimizing Micro Raman and PL Spectroscopy for Solar Cell Technological Assessment [J].
Heinz, F. D. ;
Warta, W. ;
Schubert, M. C. .
PROCEEDINGS OF THE 2ND INTERNATIONAL CONFERENCE ON CRYSTALLINE SILICON PHOTOVOLTAICS (SILICONPV 2012), 2012, 27 :208-213