Two-photon absorption in perylene derivatives

被引:46
作者
De Boni, L
Constantino, CJL
Misoguti, L
Aroca, RF
Zilio, SC
Mendonça, CR
机构
[1] Inst Fis Sao Carlos, Dept Fis & Ciencia Mat, BR-13560970 Sao Carlos, SP, Brazil
[2] Univ Windsor, Mat & Surface Sci Grp, Windsor, ON N9B 3P4, Canada
[3] UNESP, FCT, Dept Fis Quim & Biol, BR-19060900 Presidente Prudente, SP, Brazil
基金
加拿大自然科学与工程研究理事会; 巴西圣保罗研究基金会;
关键词
D O I
10.1016/S0009-2614(03)00359-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work reports on the two-photon absorption (2PA) cross-section for bis (n-butylimido) perylene (BuPTCD), bis (benzimidazo) perylene (AzoPTCD), bis (benzimidazo) thioperylene (Monothio BZP), bis (phenethylimido) perylene (PhPTCD), bis (benzylimido) perylene (BePTCD) and n-pentylimido-benzimidazo perylene (PAzoPTCD) solutions measured using the Z-scan technique with femtosecond laser pulses at 775 nm. All perylene derivatives studied present large 2PA cross-sections, only comparable to the best ones reported in the literature. The experimental 2PA cross-sections obtained for each PTCD compound are in good agreement with a simplified sum-over-state calculation. The results of the present work indicates perylene derivatives as promising materials for two-photon applications. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:744 / 749
页数:6
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