Non-, Micro-, and Mesoporous Metal-Organic Framework Isomers: Reversible Transformation, Fluorescence Sensing, and Large Molecule Separation

被引：589

作者：

Jiang, Hai-Long ^{[1
]}

Tatsu, Yoshiro ^{[1
]}

Lu, Zhang-Hui ^{[1
]}

Xu, Qiang ^{[1
]}

机构：

[1] AIST, Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 16期

关键词：

COORDINATION POLYMER; CATENATION ISOMERISM; CRYSTAL-STRUCTURE; HYDROGEN STORAGE; PORE-SIZE; FUNCTIONALIZATION; INTERPENETRATION; ADSORPTION; TOPOLOGY; DESIGN;

D O I：

10.1021/ja101541s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the first time, three novel metal-organic framework (MOF) isomers with hierachical channel sizes of nonpore or micropore or mesopore were successfully prepared by simply controlling the amounts of solvent or/and reaction temperatures/time. Strikingly, we have demonstrated the reversible transformation between the microporous and mesoporous MOFs triggered by solvent or/and temperature perturbation. The desolvated microporous MOF has been evaluated to be a promising luminescent probe for detecting small molecules, and the mesoporous MOF could be the stationary phase in high-performance liquid chromatography (HPLC) for size-exclusion separation of large dye molecules.

引用

页码：5586 / +

页数：3

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