Repetitive control and online optimization of Catofin propane process

被引:28
作者
Won, Wangyun [1 ]
Lee, Kwang Soon [1 ]
Lee, Seokho [2 ]
Jung, Chansul [2 ]
机构
[1] Sogang Univ, Dept Chem & Biomol Engn, Seoul 121742, South Korea
[2] Samsung Engn Co Ltd, Seoul 135856, South Korea
关键词
Catofin process; Online optimization; Repetitive control; Adiabatic fixed-bed reactor; SWING ADSORPTION SYSTEMS; SIMULATED MOVING BEDS; DEHYDROGENATION;
D O I
10.1016/j.compchemeng.2009.12.011
中图分类号
TP39 [计算机的应用];
学科分类号
081203 ; 0835 ;
摘要
The Catofin propane process is an emerging industrial process for propylene production through dehydrogenation of propane. It is composed of multiple adiabatic fixed-bed reactors which undergo cyclic operations where propane dehydrogenation and catalyst regeneration alternate over roughly 10-min period for each One of the major concerns in the operation of the Catofin process is maintaining the reactor at an optimum condition while overcoming gradual catalyst deactivation. Addressing this issue, an online optimization of the Catofin process combined with a repetitive control has been investigated The optimizer computes optimum initial bed temperatures for dehydrogenation and optimum air flow rate for regeneration, and the repetitive controller performs cycle-wise feedback action during regeneration to attain the target bed temperatures at the terminal time of the regeneration period Numerical studies have shown that the proposed online optimizing control system performs satisfactorily coping with the catalyst deactivation and other disturbances (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:508 / 517
页数:10
相关论文
共 17 条
[11]  
MICKLEY HS, 1965, CAN J CHEM ENG, P61
[12]  
Minkler G., 1993, THEORY APPL KALMAN F
[13]   Repetitive model predictive control applied to a simulated moving bed chromatography system [J].
Natarajan, S ;
Lee, JH .
COMPUTERS & CHEMICAL ENGINEERING, 2000, 24 (2-7) :1127-1133
[14]   Towards real-time spectroscopic process control for the dehydrogenation of propane over supported chromium oxide catalysts [J].
Nijhuis, TA ;
Tinnemans, SJ ;
Visser, T ;
Weckhuysen, BM .
CHEMICAL ENGINEERING SCIENCE, 2004, 59 (22-23) :5487-5492
[15]   COKING KINETICS OF FRESH AND THERMALLY AGED COMMERCIAL CR2O3/AL2O3 CATALYST [J].
PENA, JA ;
MONZON, A ;
SANTAMARIA, J ;
FIERRO, JLG .
APPLIED CATALYSIS A-GENERAL, 1993, 101 (02) :185-198
[16]   A survey of industrial model predictive control technology [J].
Qin, SJ ;
Badgwell, TA .
CONTROL ENGINEERING PRACTICE, 2003, 11 (07) :733-764
[17]   The use of cubic spline and far-side boundary condition for the collocation solution of a transient convection-diffusion problem [J].
Yun, Woohyun ;
Lee, Kwang Soon .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2007, 24 (02) :204-208