Synthesis, Full Characterization, and Field Effect Transistor Behavior of a Stable Pyrene-Fused N-Heteroacene with Twelve Linearly Annulated Six-Membered Rings

被引：134

作者：

Gu, Pei-Yang ^{[1
]}

Wang, Zongrui ^{[1
]}

Liu, Guangfeng ^{[1
]}

Yao, Huiying ^{[2
]}

Wang, Zilong ^{[1
]}

Li, Yang ^{[1
]}

Zhu, Jia ^{[2
]}

Li, Shuzhou ^{[1
]}

Zhang, Qichun ^{[1
,3
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China

[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

CHEMISTRY OF MATERIALS | 2017年 / 29卷 / 10期

关键词：

ORGANIC SEMICONDUCTORS; AROMATIC RINGS; LARGER ACENES; AZAACENES; MOLECULES; ELECTRONICS; HEPTACENE; HEXACENE; RIBBONS;

D O I：

10.1021/acs.chemmater.7b01318

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Synthesis, full characterization, and field effect transistor behavior of a stable pyrene-fused N-heteroacene with twelve linearly annulated six-membered rings was demonstrated in a study. The intermediate diamine was obtained as a red powder in 93% yield through the reduction reaction between 3 and lithium aluminum hydride (LiAlH4) at 60 °C. The target compound was harvested as a dark-brown powder in 52% yield through a one-step condensation reaction between another set of compounds. The thermal stability of compound 1 was evaluated by thermogravimetric analysis (TGA) under nitrogen atmosphere.

引用

页码：4172 / 4175

页数：4

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