Giant magnetocaloric effects by tailoring the phase transitions

被引:324
作者
Trung, N. T. [1 ]
Zhang, L. [1 ]
Caron, L. [1 ]
Buschow, K. H. J. [1 ]
Bruck, E. [1 ]
机构
[1] Delft Univ Technol, Fac Sci Appl, Fundamental Aspects Mat & Energy, NL-2629 JB Delft, Netherlands
关键词
cobalt alloys; ferromagnetic materials; germanium alloys; magnetic transitions; magnetocaloric effects; manganese alloys; refrigerants; solid-state phase transformations; MAGNETIC ENTROPY CHANGE; COXNI1-XMNGE SYSTEM; PRESSURE; TEMPERATURE; MNCO1-XGE;
D O I
10.1063/1.3399773
中图分类号
O59 [应用物理学];
学科分类号
摘要
The MnCoGe alloy can crystallize in either the hexagonal Ni(2)In- or the orthorhombic TiNiSi-type of structure. In both phases MnCoGe behaves like a typical ferromagnet with a second-order magnetic phase transition. For MnCoGeB(x) with B on interstitial positions, we discover a giant magnetocaloric effect associated with a single first-order magnetostructural phase transition, which can be achieved by tuning the magnetic and structural transitions to coincide. The results obtained on the MnCoGe-type alloys may be extensible to other types of magnetic materials undergoing a first-order structural transformation and can open up some possibilities for searching magnetic refrigerants for room-temperature applications.
引用
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页数:3
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