Dynamical first-order phase transition in kinetically constrained models of glasses

被引:347
作者
Garrahan, J. P. [1 ]
Jack, R. L.
Lecomte, V.
Pitard, E.
van Duijvendijk, K.
van Wijland, F.
机构
[1] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Univ Paris 07, Lab Mat & Syst Complexes, CNRS, UMR 7057, F-75205 Paris, France
[4] Univ Montpellier 2, Lab Colloides Verres & Nanomat, CNRS, UMR 5587, F-34095 Montpellier 5, France
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1103/PhysRevLett.98.195702
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We show that the dynamics of kinetically constrained models of glass formers takes place at a first-order coexistence line between active and inactive dynamical phases. We prove this by computing the large-deviation functions of suitable space-time observables, such as the number of configuration changes in a trajectory. We present analytic results for dynamic facilitated models in a mean-field approximation, and numerical results for the Fredrickson-Andersen model, the East model, and constrained lattice gases, in various dimensions. This dynamical first-order transition is generic in kinetically constrained models, and we expect it to be present in systems with fully jammed states.
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页数:4
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