A novel gel polymer electrolyte based on poly ionic liquid 1-ethyl 3-(2-methacryloyloxy ethyl) imidazolium iodide

被引：85
作者：
Yu, Bo
Zhou, Feng
Wang, Chengwei
Liu, Weimin [1 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] NW Normal Univ, Lanzhou 730000, Peoples R China
来源：
EUROPEAN POLYMER JOURNAL | 2007年 / 43卷 / 06期
基金：
中国国家自然科学基金;
关键词：
polymeric ionic liquid; ionic conductivity; electrochemical impedance spectroscopy; gel polymer electrolyte;
D O I：
10.1016/j.eurpolymj.2007.03.027
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly ionic liquid 1-ethyl 3-(2-methacryloyloxy ethyl) imidazolium iodide (PEMEImI) as a single-ion conductor was designed and synthesized. When appropriate amount of suitable plasticizers, I-2 and polyacrylonitrile (PAN) were incorporated into it, the complex formed gel polymer electrolyte. Chemical structure, thermal behavior and ionic conductive properties of the gel polymer electrolyte were investigated by Raman spectra, UV-Vis spectra, differential scanning calorimetry (DSC), and complex impedance analysis, respectively. For the new gel polymer electrolyte, the ionic conductivity of about 1 x 10(-3) S cm(-1) at room temperature was achieved. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2699 / 2707
页数：9
相关论文
共 27 条
[11]   Polymer electrolytes from PEO and novel quaternary ammonium iodides for dye-sensitized solar cells [J].
Kang, J ;
Li, W ;
Wang, X ;
Lin, Y ;
Xiao, X ;
Fang, S .
ELECTROCHIMICA ACTA, 2003, 48 (17) :2487-2491
[12]   Donor-acceptor interaction between non-aqueous solvents and I2 to generate I3-, and its implication in dye sensitized solar cells [J].
Kebede, Z ;
Lindquist, SE .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1999, 57 (03) :259-275
[13]   A novel polymer quaternary ammonium iodide and application in quasi-solid-state dye-sensitized solar cells [J].
Li, WY ;
Kang, JJ ;
Li, XP ;
Fang, SB ;
Lin, Y ;
Wang, GQ ;
Xiao, XR .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2005, 170 (01) :1-6
[14]   New class of single-ion-conducting solid polymer electrolytes derived from polyphenols [J].
Mandal, BK ;
Walsh, CJ ;
Sooksimuang, T ;
Behroozi, SJ ;
Kim, S ;
Kim, YT ;
Smotkin, ES ;
Filler, R ;
Castro, C .
CHEMISTRY OF MATERIALS, 2000, 12 (01) :6-+
[15]   Development of sol-gel redox I3-/I- electrolytes and their application in hybrid electrochromic devices [J].
Orel, B ;
Vuk, AS ;
Jese, R ;
Lianos, P ;
Stathatos, E ;
Judeinstein, P ;
Colomban, P .
SOLID STATE IONICS, 2003, 165 (1-4) :235-246
[16]   The performance and stability of ambient temperature molten salts for solar cell applications [J].
Papageorgiou, N ;
Athanassov, Y ;
Armand, M ;
Bonhote, P ;
Pettersson, H ;
Azam, A ;
Gratzel, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (10) :3099-3108
[17]   Molten and solid trialkylsulfonium iodides and their polyiodides as electrolytes in dye-sensitized nanocrystalline solar cells [J].
Paulsson, H ;
Hagfeldt, A ;
Kloo, L .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (49) :13665-13670
[18]   Quasi-solid dye sensitised solar cells filled with ionic liquid - increase in efficiencies by specific interaction between conductive polymers and gelators [J].
Shibata, Y ;
Kato, T ;
Kado, T ;
Shiratuchi, R ;
Takashima, W ;
Kaneto, K ;
Hayase, S .
CHEMICAL COMMUNICATIONS, 2003, (21) :2730-2731
[19]   ROOM-TEMPERATURE MOLTEN POLYIODIDES [J].
STEGEMANN, H ;
ROHDE, A ;
REICHE, A ;
SCHNITTKE, A ;
FULLBIER, H .
ELECTROCHIMICA ACTA, 1992, 37 (03) :379-383
[20]   Ionization reaction in iodine/pyridine solutions: What can we learn from conductivity measurements, far-infrared spectroscopy, and Raman scattering? [J].
Tassaing, T ;
Besnard, M .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (15) :2803-2808
123