Enantio- and Diastereoselective Rh(II)-Catalyzed 1,3-Dipolar Cycloadditions of Carbonyl Ylides and their Recent Applications in Complex Molecule Synthesis

被引：16
|
作者：
France, Stefan [1 ]
Phun, Lien H. [1 ]
机构：
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
来源：
CURRENT ORGANIC SYNTHESIS | 2010年 / 7卷 / 04期
关键词：
Carbonyl ylide; Diazocarbonyl compounds; 1,3-Dipolar cycloaddition; Enantioselective reactions; Heterocyclic compounds; Tandem reactions; CHIRAL DIRHODIUM(II) CARBOXYLATES; ALPHA-DIAZO KETONES; ZARAGOZIC-ACID-C; RHODIUM CARBENOIDS; ISOMUNCHNONE CYCLOADDITIONS; ASYMMETRIC CYCLOADDITIONS; ASPIDOSPERMA ALKALOIDS; DIPOLAROPHILES; CASCADE; SCOPE;
D O I：
10.2174/157017910791414463
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Rh(II)-catalyzed 1,3-dipolar cycloaddition of carbonyl ylides derived from diazocarbonyl compounds is one of the most powerful methods for the synthesis of mono-and polycyclic heterocycles. Recently, there has been a growing interest in the development of enantioselective variants of this protocol and the direct application in asymmetric total synthesis. Herein, we discuss recent advances in this field in the context of the type of chiral method used for stereoselective synthesis with particular emphasis on the levels of asymmetric induction.
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收藏
页码：332 / 347
页数：16
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