A tricarbonyl rhenium(I) complex with a pendant pyrrolidinium moiety as a robust and recyclable catalyst for chemical fixation of carbon dioxide in ionic liquid

被引:41
作者
Wong, Wing-Leung [1 ]
Cheung, Kwong-Chak [1 ]
Chan, Pak-Ho [1 ]
Zhou, Zhong-Yuan [1 ]
Lee, Kam-Han [1 ]
Wong, Kwok-Yin [1 ]
机构
[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China
关键词
D O I
10.1039/b618423e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel Re(I) complex covalently anchored with a pyrrolidinium moiety was successfully synthesized and used as an efficient and recyclable catalyst in the cycloaddition of CO2 with epoxides under mild reaction conditions to give excellent isolated yield and selectivity of cyclic carbonates in pyrrolidinium ionic liquid.
引用
收藏
页码:2175 / 2177
页数:3
相关论文
共 47 条
[1]   CO2 fixation using recoverable chromium salen catalysts:: use of ionic liquids as cosolvent or high-surface-area silicates as supports [J].
Alvaro, M ;
Baleizao, C ;
Das, D ;
Carbonell, E ;
García, H .
JOURNAL OF CATALYSIS, 2004, 228 (01) :254-258
[2]  
Anastas P. T., 1998, GREEN CHEM FRONTIERS
[3]  
[Anonymous], 1993, ELECTROCHEMICAL ELEC
[4]   Solubilities and thermodynamic properties of gases in the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate [J].
Anthony, JL ;
Maginn, EJ ;
Brennecke, JF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (29) :7315-7320
[5]   Catalysis research of relevance to carbon management: Progress, challenges, and opportunities [J].
Arakawa, H ;
Aresta, M ;
Armor, JN ;
Barteau, MA ;
Beckman, EJ ;
Bell, AT ;
Bercaw, JE ;
Creutz, C ;
Dinjus, E ;
Dixon, DA ;
Domen, K ;
DuBois, DL ;
Eckert, J ;
Fujita, E ;
Gibson, DH ;
Goddard, WA ;
Goodman, DW ;
Keller, J ;
Kubas, GJ ;
Kung, HH ;
Lyons, JE ;
Manzer, LE ;
Marks, TJ ;
Morokuma, K ;
Nicholas, KM ;
Periana, R ;
Que, L ;
Rostrup-Nielson, J ;
Sachtler, WMH ;
Schmidt, LD ;
Sen, A ;
Somorjai, GA ;
Stair, PC ;
Stults, BR ;
Tumas, W .
CHEMICAL REVIEWS, 2001, 101 (04) :953-996
[6]   An ionic liquid-supported ruthenium carbene complex: A robust and recyclable catalyst for ring-closing olefin metathesis in ionic liquids [J].
Audic, N ;
Clavier, H ;
Mauduit, M ;
Guillemin, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (31) :9248-9249
[7]   Vanadyl salen complexes covalently anchored to an imidazolium ion as catalysts for the cyanosilylation of aldehydes in ionic liquids [J].
Baleizao, C ;
Gigante, B ;
Garcia, H ;
Corma, A .
TETRAHEDRON LETTERS, 2003, 44 (36) :6813-6816
[8]   CARBON-DIOXIDE AS AN ALTERNATIVE C1 SYNTHETIC UNIT - ACTIVATION BY TRANSITION-METAL COMPLEXES [J].
BEHR, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (05) :661-678
[9]   Green processing using ionic liquids and CO2 [J].
Blanchard, LA ;
Hancu, D ;
Beckman, EJ ;
Brennecke, JF .
NATURE, 1999, 399 (6731) :28-29
[10]   Why is CO2 so soluble in imidazolium-based ionic liquids? [J].
Cadena, C ;
Anthony, JL ;
Shah, JK ;
Morrow, TI ;
Brennecke, JF ;
Maginn, EJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (16) :5300-5308