The use of solvatochromic mixed copper(II) chelates with N,N N′,N′-tetramethylethylenediamine and tropolonato or hinokitiolato ligands, [Cu(trop/hino)(tmen)]B(C6H5)4, as indicator for Lewis basicity of solvents and low-coordinating anions

被引：30
作者：
Camard, A
Ihara, Y
Murata, F
Mereiter, K
Fukuda, Y
Linert, W
机构：
[1] Vienna Univ Technol, Inst Appl Synth Chem, A-1060 Vienna, Austria
[2] Kanazawa Univ, Dept Chem, Fac Educ, Kanazawa, Ishikawa 9201192, Japan
[3] Ochanomizu Univ, Dept Chem, Fac Sci, Bunkyo Ku, Tokyo 1128610, Japan
[4] Vienna Univ Technol, Inst Chem Technol & Analyt, A-1060 Vienna, Austria
来源：
INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 02期
基金：
日本学术振兴会; 奥地利科学基金会;
关键词：
solvatochromism; Lewis basicity indicators; anion coordination; solvent effects;
D O I：
10.1016/j.ica.2004.08.021
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mixed copper(H) chelates, [Cu(trop/hino)(tmen)]B(C6H5)(4), were prepared with a tropolonato or hinokitiolato ligands (trop/hino) and N,N,N',N'-tetramethylethylenediamine (tmen). These chelates were, as expected, quite similar to the corresponding acetylacetonato analog [Cu(acac)(tmen)]B(C6H5)(4), being fairly soluble in a large number of solvents and remarkably solvatochromic in them. They were also useful as excellent Lewis basicity indicators in solution because their d-d bands continuously shift to red in wider ranges with increasing DN (donor number) of solvent. The examination on addition of various anions to these solvatochromic systems led to a quantitative view of the competition between solvent molecule and anion for coordination to metal center. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：409 / 414
页数：6
相关论文
共 20 条
[1]   Two-dimensional coordination polymers of copper(II) with oxalate: Lattice water control of structure [J].
Chen, XF ;
Cheng, P ;
Liu, X ;
Zhao, B ;
Liao, DZ ;
Yan, SP ;
Jiang, ZH .
INORGANIC CHEMISTRY, 2001, 40 (12) :2652-2659
[2]   New metallomesogens core. New copper complexes with calamitic mesophases using tropolone based ligands. Crystal structure of bis(5-octyloxytropolonato)copper [J].
Chipperfield, JR ;
Clark, S ;
Elliott, J ;
Sinn, E .
CHEMICAL COMMUNICATIONS, 1998, (02) :195-196
[3]   TAILORED MAGNETIC-PROPERTIES IN TRINUCLEAR COPPER(II) COMPLEXES - SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF COMPLEXES DERIVED FROM [1,3-PROPANEDIYLBIS(OXAMATO)]CUPRATE(II) ([CU(PBA)]2-) [J].
COSTA, R ;
GARCIA, A ;
RIBAS, J ;
MALLAH, T ;
JOURNAUX, Y ;
SLETTEN, J ;
SOLANS, X ;
RODRIGUEZ, V .
INORGANIC CHEMISTRY, 1993, 32 (17) :3733-3742
[4]   A general route to strictly dinuclear Cu(II)/Ln(III) complexes. Structural determination and magnetic behavior of two Cu(II)/Gd(III) complexes [J].
Costes, JP ;
Dahan, F ;
Dupuis, A ;
Laurent, JP .
INORGANIC CHEMISTRY, 1997, 36 (16) :3429-3433
[5]   STUDIES ON MIXED CHELATES .3. MIXED COPPER(II) CHELATES WITH N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE AND BETA-DIKETONES [J].
FUKUDA, Y ;
SHIMURA, A ;
MUKAIDA, M ;
FUJITA, E ;
SONE, K .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (06) :1265-1270
[6]  
Gutman V., 1978, DONOR ACCEPTOR APPRO
[7]   Electronic transitions and electronic structure of bis(tropolonato) copper(II) [J].
Hasegawa, M ;
Inomaki, Y ;
Inayoshi, T ;
Hoshi, T ;
Kobayashi, M .
INORGANICA CHIMICA ACTA, 1997, 257 (02) :259-264
[8]   Solvatochromic mixed-ligand copper(II) chelates with N- or N,N'-methylated ethylenediamines and tropolonato or hinokitiolato ligands [J].
Ihara, Y ;
Yoshizakiya, M ;
Yoshiyama, R ;
Sone, K .
POLYHEDRON, 1996, 15 (20) :3643-3646
[9]   Synthesis, magnetochemical studies and X-ray molecular structures of some mononuclear copper(II)-1H-pyrazole adducts and mono(μ-pyrazolate) bridged dicopper(II) complexes derived from N-salicylidenearoylhydrazines [J].
Iskander, MF ;
Khalil, TE ;
Haase, W ;
Werner, R ;
Svoboda, I ;
Fuess, H .
POLYHEDRON, 2001, 20 (22-23) :2787-2798
[10]   Syntheses of new copper(II) mixed-ligand complexes and their chromotropic properties in solution and in the solid state [J].
Jalilehvand, F ;
Ishii, Y ;
Hidai, M ;
Fukuda, Y .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (15) :3251-3256
12