Composition and thermodynamic properties of thermal plasma up to 50 kK

被引:53
作者
Coufal, O. [1 ]
机构
[1] Brno Univ Technol, Dept Elect Power Engn, Brno 61600, Czech Republic
关键词
D O I
10.1088/0022-3727/40/11/018
中图分类号
O59 [应用物理学];
学科分类号
摘要
The initial relations and the description of a method for calculating the composition and thermodynamic properties of a closed gaseous system in thermodynamic equilibrium at constant pressure and temperature are given. The essence of the method consists in the minimization of the Gibbs energy of a system in ideal state. The calculation algorithm is implemented by the Tmdgas program in the C++ language. This program is part of the database system TheCoufal, available to interested parties at http:// www. feec. vutbr. cz/similar to coufal/. The method described was used to calculate the thermodynamic properties of a system of products of the dissociation and ionization of H2O. The results have been tabulated for pressures of 1, 5 and 20 bar at temperatures ranging from ambient temperature to 50 kK.
引用
收藏
页码:3371 / 3385
页数:15
相关论文
共 15 条
[1]   Comparison of some models of reaction kinetics in HV circuit breakers with SF6 after current zero [J].
Bartlová, M ;
Coufal, O .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2002, 35 (23) :3065-3076
[2]   Electrical conductivity in SF6 thermal plasma at low temperature (1000-5000 K) [J].
Chervy, B ;
Gleizes, A .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1998, 31 (19) :2557-2565
[3]   Database system of thermodynamic properties of individual substances at high temperatures [J].
Coufal, O ;
Sezemsky, P ;
Zivny, O .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2005, 38 (08) :1265-1274
[4]   On the formal correctness of the reaction kinetics model and its solution in HV circuit breakers after current zero [J].
Coufal, O ;
Sezemsky, P .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2001, 34 (14) :2174-2184
[5]   Thermal plasma modelling [J].
Gleizes, A ;
Gonzalez, JJ ;
Freton, P .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2005, 38 (09) :R153-R183
[6]   A robust and efficient method for the computation of equilibrium composition in gaseous mixtures [J].
Godin, D ;
Trépanier, JY .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 2004, 24 (03) :447-473
[7]  
Hrabovsky M, 1998, PURE APPL CHEM, V70, P1157
[8]   Processes and properties of electric arc stabilized by water vortex [J].
Hrabovsky, M ;
Konrad, M ;
Kopecky, V ;
Sember, V .
IEEE TRANSACTIONS ON PLASMA SCIENCE, 1997, 25 (05) :833-839
[9]   MASS ACTION LAWS AND GIBBS FREE ENERGY FUNCTION [J].
SHAPIRO, NZ ;
SHAPLEY, LS .
JOURNAL OF THE SOCIETY FOR INDUSTRIAL AND APPLIED MATHEMATICS, 1965, 13 (02) :353-&
[10]   The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use [J].
Wagner, W ;
Pruss, A .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 2002, 31 (02) :387-535