η2-dba complexes of Pd(0):: The substituent effect in Suzuki-Miyaura coupling

被引：153

作者：

Fairlamb, IJS ^{[1
]}

Kapdi, AR ^{[1
]}

Lee, AF ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 24期

关键词：

D O I：

10.1021/ol048413i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The influence of aryl substituents in dibenzylidene acetone (dba) ligands, for Pd(0) complexes, has been evaluated for Suzuki-Miyaura cross-coupling reactions. Electron-withdrawing substituents such as NO2 or CF3 deactivate the catalyst species whereas strongly donating substituents such as Me increase catalytic activity over that of unsubstituted dba ligands.

引用

页码：4435 / 4438

页数：4

共 33 条

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