Benzene-Free Synthesis of Multisubstituted Catechol via Oxidative Dearomatic Reorganization

被引：6

作者：

Cao, Tongxiang ^{[1
]}

Shi, Qiu ^{[1
]}

Zhu, Shifa ^{[1
]}

机构：

[1] South China Univ Technol, Key Lab Funct Mol Engn Guangdong Prov, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China

来源：

ORGANIC LETTERS | 2021年 / 23卷 / 04期

基金：

中国博士后科学基金;

关键词：

D O I：

10.1021/acs.orglett.1c00071

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A benzene-free synthesis of multisubstituted catechol via an oxidative dearomatic reorganization is reported. This reaction tolerated a wide spectrum of functionalities, which could be applied in the synthesis of an electron-deficient arene-conjugated catechol that is difficult to access via biomimetic oxidative coupling. In addition, a diversification-oriented transformation that leveraged the versatile catechol afforded a series of functionality-rich products.

引用

页码：1411 / 1415

页数：5

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