[3] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
来源:
X-RAY ABSORPTION FINE STRUCTURE-XAFS13
|
2007年
/
882卷
关键词:
energy dispersive EXAFS;
EDXAS;
time resolved;
chemical reactions;
D O I:
暂无
中图分类号:
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Energy-dispersive X-ray absorption spectroscopy is an increasingly powerful tool for the investigation of kinetic processes in chemical systems as an element- specific local structure and electronic- state probe. In this paper we present a study of the structural evolution of the inner-sphere electron transfer reaction between [IrC1(6)](2-) and [Co(CN)(5)](3-). The experimental requirements necessary for the extraction of maximal structural and electronic information are discussed.