Time-resolved x-ray absorption spectroscopy data for the study of chemical reaction intermediate states

被引:0
作者
Moreno, Sofia Diaz [1 ]
Bowron, Daniel T. [2 ]
Evans, John [3 ]
机构
[1] Diamond Light Source, Chilton OX11 0DE, England
[2] ISIS Fac, Rutherford Appleton Lab, Didcot OX11 0QX, Oxon, England
[3] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
来源
X-RAY ABSORPTION FINE STRUCTURE-XAFS13 | 2007年 / 882卷
关键词
energy dispersive EXAFS; EDXAS; time resolved; chemical reactions;
D O I
暂无
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Energy-dispersive X-ray absorption spectroscopy is an increasingly powerful tool for the investigation of kinetic processes in chemical systems as an element- specific local structure and electronic- state probe. In this paper we present a study of the structural evolution of the inner-sphere electron transfer reaction between [IrC1(6)](2-) and [Co(CN)(5)](3-). The experimental requirements necessary for the extraction of maximal structural and electronic information are discussed.
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页码:849 / +
页数:2
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