NH3-SCR on Fe zeolite catalysts - From model setup to NH3 dosing

被引：55

作者：

Schuler, A. ^{[1
]}

Votsmeier, M. ^{[2
]}

Kiwic, P. ^{[3
]}

Gieshoff, J. ^{[2
]}

Hautpmann, W. ^{[2
]}

Drochner, A. ^{[1
]}

Vogel, H. ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Ernst Berl Inst, D-64287 Darmstadt, Germany

[2] Umicore AG & Co KG, D-63457 Hanau, Germany

[3] ETH, Inst Measurement & Control, CH-8092 Zurich, Switzerland

来源：

CHEMICAL ENGINEERING JOURNAL | 2009年 / 154卷 / 1-3期

关键词：

Fe exchanged zeolite; SCR; NH3; Ammonia; dosing; Control; Standard SCR Reaction; Fast SCR Reaction; NO2 SCR Reaction; NITRIC-OXIDE; FE-ZSM-5; CATALYST; EXCHANGED ZSM-5; DIESEL EXHAUST; REDUCTION; AMMONIA; SCR; NO; TEMPERATURE;

D O I：

10.1016/j.cej.2009.02.037

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The setup of a detailed model for the NH3-SCR process on iron exchanged zeolite catalysts is described, which takes into account the reactions of NH3, NO and NO2 occurring under typical exhaust conditions. Validation experiments fora standard SCR gas mixture show that the model is able to describe the dynamic behaviour of this system at transient temperature conditions. The model is used for the parameterization of an ammonia dosing controller. To prove the functionality of this controller it was implemented on a synthetic gas test bench and tested by a dynamic temperature experiment. This setup allows the evaluation of the parameterized controller without any disturbances from engine or injection effects. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：333 / 340

页数：8

共 28 条

[1] REACTIVITY AND PHYSICOCHEMICAL CHARACTERIZATION OF V2O5-WO3/TIO2 DE-NOX CATALYSTS
ALEMANY, LJ
LIETTI, L
FERLAZZO, N
FORZATTI, P
BUSCA, G
GIAMELLO, E
BREGANI, F
[J]. JOURNAL OF CATALYSIS, 1995, 155 (01) : 117 - 130
[2] Chemical and mechanistic aspects of the selective catalytic reduction of NOx by ammonia over oxide catalysts:: A review
Busca, G
Lietti, L
Ramis, G
Berti, F
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 18 (1-2) : 1 - 36
[3] Chatterjee D., 2006, 2006010468 SAE
[4] Chatterjee D., 2007, SAE Technical Paper
[5] Activity and durability of Fe/ZSM-5 catalysts for lean burn NOx reduction in the presence of water vapor
Chen, HY
Sachtler, WMH
[J]. CATALYSIS TODAY, 1998, 42 (1-2) : 73 - 83
[6] The simultaneous catalytic reduction of NO and N2O by NH3 using an Fe-zeolite-beta catalyst
Coq, B
Mauvezin, M
Delahay, G
Butet, JB
Kieger, S
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 27 (03) : 193 - 198
[7] Characterization and catalytic investigation of Fe-ZSM5 for urea-SCR
Devadas, Mukundan
Kroecher, Oliver
Elsener, Martin
Wokaun, Alexander
Mitrikas, George
Soeger, Nicola
Pfeifer, Marcus
Demel, Yvonne
Mussmann, Lothar
[J]. CATALYSIS TODAY, 2007, 119 (1-4) : 137 - 144
[8] Influence of NO2 on the selective catalytic reduction of NO with ammonia over Fe-ZSM5
Devadas, Mukundan
Kroecher, Oliver
Elsener, Martin
Wokaun, Alexander
Soeger, Nicola
Pfeifer, Marcus
Demel, Yvonne
Mussmann, Lothar
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 67 (3-4) : 187 - 196
[9] Devarakonda M., 2008, 2008010617 SAE
[10] Forzatti P, 1996, HETEROGEN CHEM REV, V3, P33, DOI 10.1002/(SICI)1234-985X(199603)3:1<33::AID-HCR54>3.0.CO

← 1 2 3 →