Densities and derived thermodynamic properties for the (n-heptane plus n-octane), (n-heptane plus ethanol) and (n-octane plus ethanol) systems at high pressures

被引：32

作者：

Abdussalam, Ali A. ^{[1
]}

Ivanis, Gorica R. ^{[1
]}

Radovic, Ivona R. ^{[1
]}

Kijevcanin, Mirjana Lj. ^{[1
]}

机构：

[1] Univ Belgrade, Fac Technol & Met, Karnegijeva 4, Belgrade 11120, Serbia

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2016年 / 100卷

关键词：

High pressure density; Isothermal compressibility; Isobaric thermal expansion coefficient; Binary mixtures; EXCESS MOLAR VOLUMES; BINARY-MIXTURES; ISOTHERMAL COMPRESSIBILITIES; REFRACTIVE-INDEXES; ELEVATED PRESSURES; TEMPERATURE-RANGE; LIQUID DENSITIES; 200; MPA; VISCOSITIES; HEXANE;

D O I：

10.1016/j.jct.2016.04.014

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

This work reports densities for the pure n-heptane, n-octane and ethanol at temperatures from (288.15 to 413.15) K and at pressures up to 60 MPa. The same properties were determined for the binary mixtures n-heptane + n-octane, n-heptane + ethanol and n-octane + ethanol over the temperature range (293.15-373.15) K and at pressures ranging from (0.1 to 40) MPa. Highly precise densimeter DMA HP was used for density measurements. Experimental values of densities were fitted by the modified Tammann-Tait equation. Additionally, derived volumetric properties, e.g. excess molar volumes, isothermal compressibilities and isobaric thermal expansion coefficients were calculated. The effect of pressure and temperature on the measured and derived properties was discussed. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：89 / 99

页数：11

共 38 条

[1] (p,ρ,T,x) and viscosity measurements of {x1n-heptane + (1-x1) n-octane} mixtures at high temperatures and high pressures
Abdulagatov, I. M.
Azizov, N. D.
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2006, 38 (11) : 1402 - 1415
[2] Densities and kinematic viscosities of ten binary liquid regular solutions at 308.15 and 313.15 k
Al Gherwi, Walid A.
Nhaesi, Abdulghanni H.
Asfour, Abdul-Fattah A.
[J]. JOURNAL OF SOLUTION CHEMISTRY, 2006, 35 (03) : 455 - 470
[3] Global bio-fuel processing and production trends
Balat, Mustafa
[J]. ENERGY EXPLORATION & EXPLOITATION, 2007, 25 (03) : 195 - 218
[4] Correlations for the prediction of the density and viscosity of 1-alcohols at high pressures
Cano-Gomez, Jose J.
Iglesias-Silva, Gustavo A.
Ramos-Estrada, Mariana
[J]. FLUID PHASE EQUILIBRIA, 2015, 404 : 109 - 117
[5] Viscosity and Density of Five Hydrocarbon Liquids at Pressures up to 200 MPa and Temperatures up to 473 K
Caudwell, Derek R.
Trusler, J. P. Martin
Vesovic, Velisa
Wakeham, William A.
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (02) : 359 - 366
[6] Liquid densities at elevated pressures of n-alkanes from C-5 to C-16: A critical evaluation of experimental data
Cibulka, I
Hnedkovsky, L
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (04) : 657 - 668
[7] Density of diethyl adipate using a new vibrating tube densimeter from (293.15 to 403.15) K and up to 140 MPa.: Calibration and measurements
Comunas, Maria J. P.
Bazile, Jean-Patrick
Baylaucq, Antoine
Boned, Christian
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (04) : 986 - 994
[8] Thermodynamic and acoustic properties of binary mixtures of alcohols and alkanes.: II.: Density and heat capacity of (ethanol plus n-heptane) under elevated pressures
Dzida, M
Marczak, W
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (08) : 826 - 836
[9] Volumetric and Transport Properties of Binary Mixtures of n-Octane plus Ethanol,+1-Propanol,+1-Butanol, and+1-Pentanol from (293.15 to 323.15) K at Atmospheric Pressure
Estrada-Baltazar, A.
Iglesias-Silva, G. A.
Caballero-Ceron, C.
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2013, 58 (12) : 3351 - 3363
[10] Modeling of density and calculations of derived volumetric properties for n-hexane, toluene and dichloromethane at pressures 0.1-60 MPa and temperatures 288.15-413.15 K
Ivanis, Gorica R.
Tasic, Aleksandar Z.
Radovic, Ivona R.
Djordjevic, Bojan D.
Serbanovic, Slobodan P.
Kijevcanin, Mirjana L. J.
[J]. JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2015, 80 (11) : 1423 - +

← 1 2 3 4 →