Electrodeposition of copper thin film on ruthenium - A potential diffusion barrier for Cu interconnects

被引:221
作者
Chyan, O [1 ]
Arunagiri, TN [1 ]
Ponnuswamy, T [1 ]
机构
[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA
关键词
D O I
10.1149/1.1565138
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electrochemical deposition of copper (Cu) thin film on polycrystalline ruthenium (Ru) electrode surface was investigated in a sulfuric acid plating bath. Scanning electron microscopic characterization indicated that a continuous thin Cu film (150 Angstrom and above) could be conformally coated on Ru with good control of thickness. The nucleation and growth of Cu on Ru was studied using the potentiostatic current-transient method. The results support a predominantly progressive nucleation of Cu on the Ru surface. In addition, X-ray diffraction patterns indicated (i) a principally (111) texture of the electrochemically grown Cu on Ru and (ii) the absence of any new phase or compound formation between the two metals, even after annealing up to 800degreesC. Scotch tape peel tests showed that Cu films adhered strongly to Ru, both before and after the annealing treatments. The lack of metallurgical interaction and strong adhesion between Cu and Ru at elevated temperatures underscore the potential application of Ru as a new Cu diffusion barrier. (C) 2003 The Electrochemical Society.
引用
收藏
页码:C347 / C350
页数:4
相关论文
共 26 条
[1]   Experimental and analytical study of seed layer resistance for copper damascene electroplating [J].
Broadbent, EK ;
McInerney, EJ ;
Gochberg, LA ;
Jackson, RL .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1999, 17 (06) :2584-2595
[2]   ELECTROCHEMICAL NUCLEATION .1. GENERAL-CONSIDERATIONS [J].
GUNAWARDENA, G ;
HILLS, G ;
MONTENEGRO, I ;
SCHARIFKER, B .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 138 (02) :225-239
[3]   DIFFUSION + SOLUBILITY OF COPPER IN EXTRINSIC + INTRINSIC GERMANIUM SILICON + GALLIUM ARSENIDE [J].
HALL, RN ;
RACETTE, JH .
JOURNAL OF APPLIED PHYSICS, 1964, 35 (02) :379-&
[4]   Theory of the chronoamperometric transient for electrochemical nucleation with diffusion-controlled growth [J].
Heerman, L ;
Tarallo, A .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 470 (01) :70-76
[5]   Tantalum nitride films grown by inorganic low temperature thermal chemical vapor deposition - Diffusion barrier properties in copper metallization [J].
Kaloyeros, AE ;
Chen, XM ;
Stark, T ;
Kumar, K ;
Seo, S ;
Peterson, GG ;
Frisch, HL ;
Arkles, B ;
Sullivan, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (01) :170-176
[6]   Electrodeposition and nucleation of copper at nitrogen-incorporated tetrahedral amorphous carbon electrodes in basic ambient temperature chloroaluminate melts [J].
Lee, JJ ;
Miller, B ;
Shi, X ;
Kalish, R ;
Wheeler, KA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (03) :C183-C190
[7]  
MASSALSKI TB, 1990, BINARY ALLOY PHASE D, P1467
[8]  
Murarka S. P., 2000, COPPER FUNDAMENTAL M
[9]   Electrochemical deposition of copper on n-Si/TiN [J].
Oskam, G ;
Vereecken, PM ;
Searson, PC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (04) :1436-1441
[10]  
PALLEAN J, 1994, MATER RES SOC S P, V337, P25