Highly selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis (hydroxymethyl)furan over metal-oxide supported Pt catalysts: The role of basic sites

被引：24

作者：

Wang, Jian ^{[1
,2
]}

Zhao, Jiarui ^{[2
,3
]}

Fu, Junhong ^{[2
]}

Miao, Cuilan ^{[2
]}

Jia, Songyan ^{[1
]}

Yan, Peifang ^{[2
]}

Huang, Jiahui ^{[2
,3
]}

机构：

[1] Shenyang Univ Chem Technol, Coll Chem Engn, Shenyang 110142, Liaoning, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

APPLIED CATALYSIS A-GENERAL | 2022年 / 643卷

基金：

国家自然科学基金国际合作与交流项目; 国家重点研发计划;

关键词：

Metal oxide; Basicity; Acidity; 5-hydroxymethylfurfural; Hydrogenation; LIQUID-PHASE HYDROGENATION; BIOMASS; 2,5-BIS(HYDROXYMETHYL)FURAN; NANOPARTICLES; REDUCTION;

D O I：

10.1016/j.apcata.2022.118762

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (BHMF) is an important reaction for biomass valorization. We report that metal oxides (including MgO, ZnO, SiO2 and TiO2) supported Pt catalysts show vastly different BHMF selectivity towards the hydrogenation of HMF. The basic metal oxide MgO supported Pt catalyst affords 99 % selectivity of BHMF, while the typical acidic metal oxide TiO2 supported Pt catalyst displays only 28 % selectivity of BHMF. HMF chemisorption on these catalysts show that the basic sites of metal oxide bonding to the C--O group of HMF promote the BHMF selectivity, while the acidic sites of metal oxide favor the adsorption of C--C group of HMF, which decreases the BHMF selectivity. It is proposed that the cooperation between basic sites and Pt atoms (activating H2) boosted the BHMF selectivity. Comprehensive studies including reactivity, recyclability, stability, solvent effect on the Pt/MgO catalyst were also carried out.

引用

页数：7

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