Structural and Catalytic Performance of a Polyoxometalate-Based Metal-Organic Framework Having a Lanthanide Nanocage as a Secondary Building Block

被引：94
|
作者：
Dang, Dongbin [1 ,2 ]
Bai, Yan [2 ]
He, Cheng [1 ]
Wang, Jian [1 ]
Duan, Chunying [1 ]
Niu, Jingyang [2 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] Henan Univ, Inst Mol & Crystal Engn, Sch Chem & Chem Engn, Kaifeng 475004, Peoples R China
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 04期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
DINUCLEAR ZN(II) COMPLEX; TRANSITION-STATE; RNA MODELS; CLEAVAGE; PHOSPHATE; CLUSTERS; SORPTION; HYDROLYSIS; EFFICIENT; POLYMER;
D O I：
10.1021/ic901504q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A polyoxometalate-based lanthanide-organic framework was achieved using the {[Ho-4(dpdo)(8)(H2O)(16)BW12O40] (H2O)(2)}(7+) nanocage as a secondary building block for the heterogeneous catalysis of phosphodiester cleavage in an aqueous solution.
引用
收藏
页码：1280 / 1282
页数：3
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