Acrylic Polymer Composition Suitable for Ion Delivery and Selective Detection of Proton, and Hydroxyl and Cu(II) Ions

被引：0

作者：

Lee, Dahye ^{[1
]}

Woo, Heejung ^{[1
]}

Do, Jung Yun ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Chem Educ, Pusan 609735, South Korea

来源：

POLYMER-KOREA | 2014年 / 38卷 / 06期

关键词：

proton transfer in polymer film; UV-polymerizaion; p-methylred; rhodamine; copper(II) ion detection; PH; SENSORS; GREEN; FILMS;

D O I：

10.7317/pk.2014.38.6.801

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ion diffusion and chemical binding to acrylic polymer were investigated in a solid film. The composition of acrylic monomers containing amino group and carboxylic acid was adjusted for rapid ion migration in the film p-Methylred (PMR) and phenolphthalein derivatives were optically sensitive to the concentration of proton and hydroxyl anion, respectively and verified the ion migration through the film layers. A rapid proton migration was observed in the film of a high amino content. On the other hand, OH- migration occurred rapidly in a high content of carboxylic acid group. The proton migration occurred through the internal layer as well as surface layer of a film and was reversible during 50 repetition examination. Copper(II) ion migration was examined with a Rhodamine-containing polymer film. The light absorption and emission spectra of a Rhodamine-Cu complex showed the key contribution of carboxylic acid group to the Cu(II) migration in a film

引用

页码：801 / 808

页数：8

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